The chemistry and applications of multimetallic salen complexes

被引：136
作者：
Clarke, Ryan M. [1 ]
Storr, Tim [1 ]
机构：
[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
来源：
DALTON TRANSACTIONS | 2014年 / 43卷 / 25期
基金：
加拿大自然科学与工程研究理事会;
关键词：
REDOX-ACTIVE LIGANDS; ASYMMETRIC NITROALDOL REACTIONS; SPIN-POLARIZATION MECHANISM; FUSED SALPHEN COMPLEXES; SCHIFF-BASE MACROCYCLES; RING-OPENING REACTIONS; GALACTOSE-OXIDASE; ENANTIOSELECTIVE POLYMERIZATION; ALPHA; BETA-UNSATURATED IMIDES; SPECTROSCOPIC PROPERTIES;
D O I：
10.1039/c4dt00591k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Multimetallic salen complexes have found utility in a number of fields from materials chemistry to catalysis. The objective of this perspective is to discuss the development of new synthetic strategies to multitopic ligands based on Schiff base chemistry, and the isolation and study of the resulting metal complexes. Developments in catalysis, magnetism, electronic structure, and small-molecule sensing are presented demonstrating the considerable potential of these ligand constructs in facilitating new chemistry.
引用
收藏
页码：9380 / 9391
页数：12
相关论文
共 113 条
  • [1] Enantioselective Polymerization of Epoxides Using Biaryl-Linked Bimetallic Cobalt Catalysts: A Mechanistic Study
    Ahmed, Syud M.
    Poater, Albert
    Childers, M. Ian
    Widger, Peter C. B.
    LaPointe, Anne M.
    Lobkovsky, Emil B.
    Coates, Geoffrey W.
    Cavallo, Luigi
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (50) : 18901 - 18911
  • [2] Synthesis and crystal structure of a novel triangular macrocyclic molecule, tris(H2saloph), and its water complex
    Akine, S
    Taniguchi, T
    Nabeshima, T
    [J]. TETRAHEDRON LETTERS, 2001, 42 (50) : 8861 - 8864
  • [3] Helical metallohost-guest complexes via site-selective transmetalation of homotrinuclear complexes
    Akine, Shigehisa
    Taniguchi, Takanori
    Nabeshima, Tatsuya
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) : 15765 - 15774
  • [4] Stepwise Helicity Inversions by Multisequential Metal Exchange
    Akine, Shigehisa
    Sairenji, Shiho
    Taniguchi, Takanori
    Nabeshima, Tatsuya
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (35) : 12948 - 12951
  • [5] Modulation of Multimetal Complexation Behavior of Tetraoxime Ligand by Covalent Transformation of Olefinic Functionalities
    Akine, Shigehisa
    Kagiyama, Satoko
    Nabeshima, Tatsuya
    [J]. INORGANIC CHEMISTRY, 2010, 49 (05) : 2141 - 2152
  • [6] AUDEBERT P, 1991, NEW J CHEM, V15, P235
  • [7] Metal complexes for DNA-mediated charge transport
    Barton, Jacqueline K.
    Olmon, Eric D.
    Sontz, Pamela A.
    [J]. COORDINATION CHEMISTRY REVIEWS, 2011, 255 (7-8) : 619 - 634
  • [8] BOTTCHER A, 1993, INORG CHEM, V32, P4131
  • [9] BOTTCHER A, 1994, Z NATURFORSCH B, V49, P1089
  • [10] Modular Synthesis of Heterobimetallic Salen Structures Using Metal Templation
    Castilla, Ana M.
    Currell, Simona
    Escudero-Adan, Eduardo C.
    Martinez Belmonte, Marta
    Benet-Buchholz, Jordi
    Kleij, Arjan W.
    [J]. ORGANIC LETTERS, 2009, 11 (22) : 5218 - 5221
12345678910