The chemistry and applications of multimetallic salen complexes

被引：141

作者：

Clarke, Ryan M. ^{[1
]}

Storr, Tim ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 25期

基金：

加拿大自然科学与工程研究理事会;

关键词：

REDOX-ACTIVE LIGANDS; ASYMMETRIC NITROALDOL REACTIONS; SPIN-POLARIZATION MECHANISM; FUSED SALPHEN COMPLEXES; SCHIFF-BASE MACROCYCLES; RING-OPENING REACTIONS; GALACTOSE-OXIDASE; ENANTIOSELECTIVE POLYMERIZATION; ALPHA; BETA-UNSATURATED IMIDES; SPECTROSCOPIC PROPERTIES;

D O I：

10.1039/c4dt00591k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Multimetallic salen complexes have found utility in a number of fields from materials chemistry to catalysis. The objective of this perspective is to discuss the development of new synthetic strategies to multitopic ligands based on Schiff base chemistry, and the isolation and study of the resulting metal complexes. Developments in catalysis, magnetism, electronic structure, and small-molecule sensing are presented demonstrating the considerable potential of these ligand constructs in facilitating new chemistry.

引用

页码：9380 / 9391

页数：12

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