A Novel Supramolecular Complex Based on Zaltoprofen Ligand: Synthesis, Crystal Structure, and Properties

被引：0

作者：

Yin, Xia ^{[1
]}

Tang, Jin-Niu ^{[2
]}

Pan, Gang-Hong ^{[2
]}

Tian, Wei-Man ^{[1
]}

Xu, Wen-Jia ^{[2
]}

Huang, Zhong-Jing ^{[2
]}

机构：

[1] 2 Middle Sch Dongkou Hunan, Dongkou, Peoples R China

[2] Guangxi Univ Nationalities, Coll Chem & Chem Engn, Nanning, Peoples R China

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2014年 / 593卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Crystal structure; photoluminescence properties; zaltoprofen; pi-pi stacking; SILVER(I) COORDINATION POLYMERS; THERMAL-ANALYSIS; HYDROGEN-BONDS; ARCHITECTURES; ISOMERISM; SPACERS; NETWORK; CHAINS;

D O I：

10.1080/15421406.2013.858584

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel metal-organic supramolecular complex [Zn-2 (Zaltoprofen) 2(phen) 2] (where Zaltoprofen = 5-(1-carboxyethyl)-2-(phenylthio) phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized under hydrothermal condition and characterized by single crystal X-ray diffraction, elemental analysis, spectral method (IR), powder Xray diffraction (XRD), electronic Spectra (UV-vis), and fluorescent properties. The compound crystallizes in the monoclinic P2(1)/c space group. [Zn-2(Zaltoprofen) 2(phen) 2] features 0-D structural, the pi-pi stacking interactions and C-H center dot center dot center dot O hydrogen-bonds play a vital role in determining the crystal packing and construction of the extended 3-D supramolecular network.

引用

页码：179 / 186

页数：8

共 32 条

[11] Structural interconversion controlled by hydrogen-bond interactions: A mononuclear copper triamine complex and a polynuclear copper triamine sheet [J].