A Novel Supramolecular Complex Based on Zaltoprofen Ligand: Synthesis, Crystal Structure, and Properties

被引：0
作者：
Yin, Xia [1 ]
Tang, Jin-Niu [2 ]
Pan, Gang-Hong [2 ]
Tian, Wei-Man [1 ]
Xu, Wen-Jia [2 ]
Huang, Zhong-Jing [2 ]
机构：
[1] 2 Middle Sch Dongkou Hunan, Dongkou, Peoples R China
[2] Guangxi Univ Nationalities, Coll Chem & Chem Engn, Nanning, Peoples R China
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2014年 / 593卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Crystal structure; photoluminescence properties; zaltoprofen; pi-pi stacking; SILVER(I) COORDINATION POLYMERS; THERMAL-ANALYSIS; HYDROGEN-BONDS; ARCHITECTURES; ISOMERISM; SPACERS; NETWORK; CHAINS;
D O I：
10.1080/15421406.2013.858584
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel metal-organic supramolecular complex [Zn-2 (Zaltoprofen) 2(phen) 2] (where Zaltoprofen = 5-(1-carboxyethyl)-2-(phenylthio) phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized under hydrothermal condition and characterized by single crystal X-ray diffraction, elemental analysis, spectral method (IR), powder Xray diffraction (XRD), electronic Spectra (UV-vis), and fluorescent properties. The compound crystallizes in the monoclinic P2(1)/c space group. [Zn-2(Zaltoprofen) 2(phen) 2] features 0-D structural, the pi-pi stacking interactions and C-H center dot center dot center dot O hydrogen-bonds play a vital role in determining the crystal packing and construction of the extended 3-D supramolecular network.
引用
收藏
页码：179 / 186
页数：8
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