Developing WO3 as high-performance anode material for lithium-ion batteries

被引:36
作者
Xiao, Ying [1 ]
Jiang, Minxia [1 ]
Cao, Minhua [1 ]
机构
[1] Beijing Inst Technol, Sch Chem & Chem Engn, Key Lab Cluster Sci,Minist Educ China, Beijing Key Lab Photoelect Electrophoton Convers, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
WO3; Nanoparticles; Composite materials; Electrochemical performance; Lithium-ion batteries; ELECTROCHEMICAL PROPERTIES; ELECTROCATALYTIC ACTIVITY; CARBON; SHELL; NANOTUBES; HOLLOW; CLOTH;
D O I
10.1016/j.matlet.2020.129129
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Herein, we report on the development of WO3/C hybrid as an anode for lithium-ion batteries. The conductivity and stability of WO3 electrode are boosted by hybrid carbon; the ion transfer length can be reduced by the small size of active material. These effects endow the resultant anode exhibiting favorable lithium storage properties in term of high efficiency, robust cycling stability and high rate capability. Resultantly, the reversible capacities of 833.4 and 528.3 mAh g(-1) could be delivered after 100 discharge/charge cycles at 100 mA g(-1) and 1300 deep discharge/charge cycles at 500 mA g(-1), respectively. Such a performance is superior to those of the previously reported WO3-based materials. Considering the simplification of the fabrication process and the outstanding performance, the WO3/C hybrid is deemed to be a promising anode material substituting for commercial graphite. (c) 2020 Elsevier B.V. All rights reserved.
引用
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页数:4
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