A general derivation and quantification of the third law of thermodynamics

被引:115
作者
Masanes, Lluis [1 ]
Oppenheim, Jonathan [1 ]
机构
[1] UCL, Dept Phys & Astron, London WC1E 6BT, England
来源
NATURE COMMUNICATIONS | 2017年 / 8卷
基金
英国工程与自然科学研究理事会;
关键词
GROUND-STATE; QUANTUM; THEOREM; COST;
D O I
10.1038/ncomms14538
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The most accepted version of the third law of thermodynamics, the unattainability principle, states that any process cannot reach absolute zero temperature in a finite number of steps and within a finite time. Here, we provide a derivation of the principle that applies to arbitrary cooling processes, even those exploiting the laws of quantum mechanics or involving an infinite-dimensional reservoir. We quantify the resources needed to cool a system to any temperature, and translate these resources into the minimal time or number of steps, by considering the notion of a thermal machine that obeys similar restrictions to universal computers. We generally find that the obtainable temperature can scale as an inverse power of the cooling time. Our results also clarify the connection between two versions of the third law (the unattainability principle and the heat theorem), and place ultimate bounds on the speed at which information can be erased.
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页数:7
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