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Preparation and characterization of poly(lactic acid)-grafted TiO2 nanoparticles with improved dispersions
被引:74
作者:
Luo, Yan-Bing
[1
]
Wang, Xiu-Li
[1
]
Xu, Da-Yun
[1
]
Wang, Yu-Zhong
[1
]
机构:
[1] Sichuan Univ, State Key Lab Polymer Mat Engn, Coll Chem, Ctr Degradable & Flame Retardant Polymer Mat ERCE, Chengdu 610064, Peoples R China
基金:
美国国家科学基金会;
关键词:
TiO2;
nanoparticle;
Poly(lactic acid);
Graft;
FTIR;
XPS;
CHARGE-TRANSFER;
SURFACE;
NANOCOMPOSITE;
ACID;
POLYMERIZATION;
SILICA;
ADSORPTION;
FILMS;
DISPERSIBILITY;
FABRICATION;
D O I:
10.1016/j.apsusc.2009.02.074
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Poly(lactic acid) (PLA)-grafted TiO2 particles were prepared by in situ melt polycondensation of lactic acid onto the surface of TiO2 nanoparticles. The resulting products were characterized by FTIR, XPS, TG-FTIR, XRD analysis and electron microscopy observation so as to have a better understanding of bonding between the graft polymer and nanoparticles. New characteristic peaks of Ti-carboxylic coordination bond, the changes in the relative intensities of the infrared absorption bands of graft polymer and the two decomposition stage of PLA-grafted TiO2 confirmed that PLA was grafted on the surface of TiO2 nanoparticles. By attachment of PLA, the PLA-grafted TiO2 samples exhibited much better dispersion and a slightly larger particle size than bare TiO2 particles. PLA-grafted TiO2 nanoparticles will find wide applications in biomedical and eco-friendly materials, especially as fillers in PLA matrix. (C) 2009 Elsevier B. V. All rights reserved.
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页码:6795 / 6801
页数:7
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