Hierachical porous carbon structures from cellulose acetate fibers

被引:67
作者
Polarz, S
Smarsly, B
Schattka, JH
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[2] Univ Toronto, Lash Miller Chem Labs, Toronto, ON M5S 3H6, Canada
[3] Univ New Mexico, Adv Mat Lab, Albuquerque, NM 87106 USA
关键词
D O I
10.1021/cm011271r
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study describes the transformation of cellulose acetate filters into porous carbon structures by a facile, direct process. Filters from cigarettes were used as the source for cellulose acetate filters. Carbon was obtained by high-temperature treatment under inert conditions without extensive preparative methods. The resulting carbon materials showed structural features on different length scales ranging from the micrometer to the nanometer scale. The materials were investigated using imaging techniques (scanning electron microscopy, SEM; transmission electron microcopy, TEM; and confocal Raman microscopy); the internal structure was investigated with Raman spectroscopy, wide-angle X-ray scattering (WAXS), small-angle X-ray scattering; and the porosity was explored using nitrogen sorption analysis.
引用
收藏
页码:2940 / 2945
页数:6
相关论文
共 29 条
[1]   Tailored porous materials [J].
Barton, TJ ;
Bull, LM ;
Klemperer, WG ;
Loy, DA ;
McEnaney, B ;
Misono, M ;
Monson, PA ;
Pez, G ;
Scherer, GW ;
Vartuli, JC ;
Yaghi, OM .
CHEMISTRY OF MATERIALS, 1999, 11 (10) :2633-2656
[2]  
BRINKER CJ, 1990, SOL GEL SCI PHYSICS
[3]  
Chomski E, 2000, ADV MATER, V12, P1071, DOI 10.1002/1521-4095(200007)12:14<1071::AID-ADMA1071>3.0.CO
[4]  
2-J
[5]   Ordered mesoporous materials [J].
Ciesla, U ;
Schüth, F .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (2-3) :131-149
[6]  
GREGG SJ, 1982, ADSORPTION SURFACE A, V2
[7]   THE SOL-GEL PROCESS [J].
HENCH, LL ;
WEST, JK .
CHEMICAL REVIEWS, 1990, 90 (01) :33-72
[8]   High-yield carbonization of cellulose by sulfuric acid impregnation [J].
Kim, DY ;
Nishiyama, Y ;
Wada, M ;
Kuga, S .
CELLULOSE, 2001, 8 (01) :29-33
[9]   Control of pore structure in carbon [J].
Kyotani, T .
CARBON, 2000, 38 (02) :269-286
[10]   THE SURFACE PROPERTIES OF CARBON .2. THE EFFECT OF CAPILLARY CONDENSATION AT LOW RELATIVE PRESSURES UPON THE DETERMINATION OF SURFACE AREA [J].
LAMOND, TG ;
MARSH, H .
CARBON, 1964, 1 (03) :281-292