Immobilization of borate waste simulate in cement-water extended polyester composite based on poly(ethylene terephthalate) waste

被引:13
作者
Eskander, S. B. [1 ]
Bayoumi, T. A. [1 ]
Tawfik, M. E. [1 ]
机构
[1] Natl Res Ctr, Dept Polymers & Pigments, Cairo, Egypt
关键词
compressive strength; durability index; freezing/thawing test; PET waste; polymer modified cement; porosity;
D O I
10.1080/03602550600723415
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Modified composite from water extended polyester (WEP); based on the recycled poly(ethylene terephthalate), (PET), and ordinary Portland cement (OPC) is a candidate matrix for processing borate waste solutions originating from the primary coolant circuit of pressurized water reactors (PWRs). This part of the work discusses the frost resistance of this polymer-modified cement composite (PCC) during the disposal course. Frost resistance is assessed for the candidate PCC after 115 cycles of freezing and thawing treatment (FTC) by evaluating their durability index, compressive strength, apparent porosity, volume of open pores, water absorption, and bulk density. Infrared (IR) and X-ray diffraction (XRD) as non-destructive analyses were performed for the candidate PCC before and after the freezing/thawing treatment to follow the changes that may take place during the hydration regime. The results obtained indicate that the candidate-modified cement composite exhibits acceptable resistance to freezing and thawing treatment even at very exaggerating conditions (-19 degrees C and +60 degrees C).
引用
收藏
页码:939 / 945
页数:7
相关论文
共 26 条
[1]  
Amelina EA, 1997, COLLOID J+, V59, P96
[2]  
*BRIT STAND I, 1969, PORTL CEM
[3]  
Bull C.B., 1975, IUGG CHRON, V102, P163
[4]  
Darr G.M., 1973, MAT STRUCTURES, V6, P185
[5]  
Gani M. S. J., 1997, CEMENT CONCRETE
[6]   Ettringite and C-S-H Portland cement phases for waste ion immobilization: A review [J].
Gougar, MLD ;
Scheetz, BE ;
Roy, DM .
WASTE MANAGEMENT, 1996, 16 (04) :295-303
[7]   MANAGEMENT OF LOW AND INTERMEDIATE LEVEL RADIOACTIVE-WASTES BY INCORPORATION INTO WATER EXTENDED POLYESTERS [J].
IKLADIOUS, NE ;
TAWFIK, ME ;
GHATTAS, NK .
JOURNAL OF ELASTOMERS AND PLASTICS, 1992, 24 (04) :363-382
[8]  
*INT AT EN AG, 1964, TECHN REP SER IAEA, V98
[9]   Porosity, pore size distribution and in situ strength of concrete [J].
Kumar, R ;
Bhattacharjee, B .
CEMENT AND CONCRETE RESEARCH, 2003, 33 (01) :155-164
[10]   ION DIFFUSION IN MICROCRACKED CONCRETE [J].
LOCOGE, P ;
MASSAT, M ;
OLLIVIER, JP ;
RICHET, C .
CEMENT AND CONCRETE RESEARCH, 1992, 22 (2-3) :431-438