Electronic Effects in the Reactions of Olefin-Coordinated Gold Carbene Complexes

被引：43
|
作者：
Fedorov, Alexey [1 ]
Chen, Peter [1 ]
机构：
[1] ETH, Chim Organ Lab, CH-8093 Zurich, Switzerland
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 05期
关键词：
KINETIC METHOD; CONSTANTS; CATALYST; ENYNES;
D O I：
10.1021/om800795v
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The influence of electronic effects on cyclopropanation, cross-meta thesis, and olefin loss reactions was probed in the gas phase for the series of adducts formed by para-substituted benzylidene gold carbenes and cis-dimethoxyethylene. This information sheds light on rate-determining transition states associated with every process and suggests that tuning of the selectivity is possible.
引用
收藏
页码：1278 / 1281
页数：4
相关论文
共 50 条
  • [31] SYNTHESIS AND REACTIONS OF A CHELATED CARBENE-OLEFIN COMPLEX OF CYCLOPENTADIENYLIRON
    REGER, DL
    KLAEREN, SA
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 342 (01) : 77 - 85
  • [32] Carbene Transfer Reactions from Chromium(0) to Gold(I): Synthesis and Reactivity of New Fischer-Type Gold(I) Alkenyl Carbene Complexes
    Fananas-Mastral, Martin
    Aznar, Fernando
    ORGANOMETALLICS, 2009, 28 (03) : 666 - 668
  • [33] PRESSURE ACCELERATION OF [2 + 2] CYCLOADDITION REACTIONS ON THE COORDINATED LIGAND OF CHROMIUM AND TUNGSTEN PENTACARBONYL CARBENE COMPLEXES
    PIPOH, R
    VANELDIK, R
    WANG, SLB
    WULFF, WD
    ORGANOMETALLICS, 1992, 11 (01) : 490 - 492
  • [34] Perfluoro- olefin, carbene, and carbyne complexes of (PNP)Rh
    Pell, Christopher
    Zhu, Yanjun
    Huacuja, Rafael
    Ozerov, Oleg
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [35] Molecular modeling of the olefin metathesis by tungsten(0) carbene complexes
    Tlenkopatchev, M
    Fomine, S
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 630 (02) : 157 - 168
  • [36] CARBENE COMPLEXES IN STEREOSELECTIVE CYCLOADDITION REACTIONS
    DOTZ, KH
    NEW JOURNAL OF CHEMISTRY, 1990, 14 (6-7) : 433 - 445
  • [37] INTERACTION OF COORDINATED GOLD COMPLEXES WITH DNA
    MIRABELLI, CK
    SUNG, CM
    BARTUS, HE
    CROOKE, ST
    PROCEEDINGS OF THE AMERICAN ASSOCIATION FOR CANCER RESEARCH, 1983, 24 (MAR): : 293 - 293
  • [38] Gold-Catalyzed Carbene Transfer Reactions
    Shin, Seunghoon
    HOMOGENEOUS GOLD CATALYSIS, 2015, 357 : 25 - 62
  • [39] Gold Complexes with ADAP Ligands: Effect of Bulkiness in Catalytic Carbene Transfer Reactions (ADAP = Alkoxydiaminophosphine)
    Diego Pizarro, Juan
    Molina, Francisco
    Fructos, Manuel R.
    Perez, Pedro J.
    ORGANOMETALLICS, 2020, 39 (13) : 2553 - 2559
  • [40] A bonding model for gold(I) carbene complexes
    Benitez, Diego
    Shapiro, Nathan D.
    Tkatchouk, Ekaterina
    Wang, Yiming
    Goddard, William A., III
    Toste, F. Dean
    NATURE CHEMISTRY, 2009, 1 (06) : 482 - 486
12345