Atomic Layer Deposition of ZrO2 and HfO2 Nanotubes by Template Replication

被引:27
作者
Gu, Diefeng [1 ,2 ]
Baumgart, Helmut [1 ,2 ]
Namkoong, Gon [1 ,2 ]
Abdel-Fattah, Tarek M. [2 ,3 ]
机构
[1] Old Dominion Univ, Dept Elect Engn, Norfolk, VA 23529 USA
[2] Appl Res Ctr, Newport News, VA 23606 USA
[3] Christopher Newport Univ, Dept Biol Chem & Environm Sci, Newport News, VA 23606 USA
关键词
atomic layer deposition; hafnium compounds; nanotechnology; nanotubes; porosity; scanning electron microscopy; X-ray chemical analysis; zirconium compounds; FABRICATION; MEMBRANES; ARRAYS;
D O I
10.1149/1.3070617
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Highly ordered zirconia and hafnia nanotubes were fabricated by atomic layer deposition (ALD) within the anodic alumina oxide (AAO) template. Scanning electron microscopy and energy-dispersive spectroscopy were used to characterize the morphology and elemental compositions of the different ALD coatings. The diameters of the AAO pores are in the range of 200-300 nm with a thickness of 60 mu m. The results indicated that the freestanding nanotubes were uniformly grown through the entire template thickness. The ALD process conformally replicated the AAO template dimensions. The number of ALD cycles controlled the resultant nanotube wall thickness.
引用
收藏
页码:K25 / K28
页数:4
相关论文
共 16 条
[1]   Pyrolytic synthesis of carbon nanotubes from sucrose on a mesoporous silicate [J].
Abdel-Fattah, Tarek ;
Siochi, Emilie J. ;
Crooks, Roy E. .
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2006, 14 (04) :585-594
[2]   Atomic layer deposition of SiO2 and TiO2 in alumina tubular membranes:: Pore reduction and effect of surface species on gas transport [J].
Cameron, MA ;
Gartland, IP ;
Smith, JA ;
Diaz, SF ;
George, SM .
LANGMUIR, 2000, 16 (19) :7435-7444
[3]   Fabrication of silica nanotube arrays from vertical silicon nanowire templates [J].
Fan, R ;
Wu, YY ;
Li, DY ;
Yue, M ;
Majumdar, A ;
Yang, PD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (18) :5254-5255
[4]   Single-crystal gallium nitride nanotubes [J].
Goldberger, J ;
He, RR ;
Zhang, YF ;
Lee, SW ;
Yan, HQ ;
Choi, HJ ;
Yang, PD .
NATURE, 2003, 422 (6932) :599-602
[5]   Experimental study of ALD HfO2 deposited on strained silicon-on-insulator and standard SOI [J].
Gu, D. ;
Tapily, K. ;
Shrestha, P. ;
Zhu, M. Y. ;
Celler, G. ;
Baumgart, H. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (06) :G129-G133
[6]   Atomic layer deposition of hafnium and zirconium oxides using metal amide precursors [J].
Hausmann, DM ;
Kim, E ;
Becker, J ;
Gordon, RG .
CHEMISTRY OF MATERIALS, 2002, 14 (10) :4350-4358
[7]  
Kelsall R, 2006, NANOSCALE SCI TECHNO
[8]   Preparation of tin dioxide nanotubes via electrosynthesis in a template [J].
Lai, Min ;
Gonzalez Martinez, Jose A. ;
Graetzel, Michael ;
Riley, D. Jason .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (27) :2843-2845
[9]   Antibody-based bio-nanotube membranes for enantiomeric drug separations [J].
Lee, SB ;
Mitchell, DT ;
Trofin, L ;
Nevanen, TK ;
Söderlund, H ;
Martin, CR .
SCIENCE, 2002, 296 (5576) :2198-2200
[10]   TEMPLATE SYNTHESIS OF ELECTRONICALLY CONDUCTIVE POLYMER NANOSTRUCTURES [J].
MARTIN, CR .
ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (02) :61-68