State analysis of nitrogen in carbon film derived from polyimide kapton

被引：59
作者：
Konno, H
Nakahashi, T
Inagaki, M
机构：
[1] Faculty of Engineering, Hokkaido University, Sapporo, 060, Kita-ku
来源：
CARBON | 1997年 / 35卷 / 05期
基金：
日本学术振兴会;
关键词：
carbon precursor; carbonization; heat treatment; photoelectron spectroscopy;
D O I：
10.1016/S0008-6223(97)00022-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The carbon films prepared from polyimide Kapton were investigated by XPS and elemental analysis. The chemical states of carbon and nitrogen gradually changed with carbonization temperature and the changes in the peak intensity ratio of I[N1s]/I[C1s] by XPS were consistent with N/C mole ratios by elemental analysis. The N1s peak around 401 eV which was a main component at 1200 degrees C was considered to correspond to quaternary species such as a pyrrole type nitrogen. This species may exist in the carbon films prepared at 2000 degrees C and affect their properties. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：669 / 674
页数：6
相关论文
共 17 条
  • [1] BOUGERETTE C, 1992, J MATER RES, V7, P1158
  • [2] VARIATION OF NITROGEN-CONTENT AND FUNCTIONALITY WITH RANK FOR SOME UK BITUMINOUS COALS
    BURCHILL, P
    WELCH, LS
    [J]. FUEL, 1989, 68 (01) : 100 - 104
  • [3] BURSTING OF GRAPHITIZED POLYIMIDE FILMS THROUGH THE LIBERATION OF INCLUDED NITROGEN
    HATORI, H
    YAMADA, Y
    SHIRAISHI, M
    [J]. CARBON, 1994, 32 (02) : 359 - 361
  • [4] GRAPHITE FILMS PREPARED FROM CARBONIZED POLYIMIDE FILMS
    HISHIYAMA, Y
    YOSHIDA, A
    KABURAGI, Y
    INAGAKI, M
    [J]. CARBON, 1992, 30 (03) : 333 - 337
  • [5] FORMATION OF PORES IN CARBONIZED POLYIMIDE FILM KAPTON BY HIGH-TEMPERATURE HEAT-TREATMENT
    HISHIYAMA, Y
    YOSHIDA, A
    KABURAGI, Y
    INAGAKI, M
    [J]. CARBON, 1992, 30 (03) : 517 - 519
  • [6] HISHIYAMA Y, UNPUB CARBON
  • [7] STRUCTURAL AND TEXTURAL CHANGES FROM POLYIMIDE KAPTON TO GRAPHITE .2. MAGNETORESISTANCE AND X-RAY-DIFFRACTION
    INAGAKI, M
    HISHIYAMA, Y
    [J]. JOURNAL OF MATERIALS RESEARCH, 1992, 7 (05) : 1174 - 1177
  • [8] EFFECT OF HEATING RATE DURING CARBONIZATION ON GRAPHITIZATION OF CARBON-FILMS DERIVED FROM AROMATIC POLYIMIDES
    INAGAKI, M
    HISHIYAMA, Y
    KABURAGI, Y
    [J]. CARBON, 1994, 32 (04) : 637 - 639
  • [9] CARBONIZATION OF POLYIMIDE FILM KAPTON
    INAGAKI, M
    HARADA, S
    SATO, T
    NAKAJIMA, T
    HORINO, Y
    MORITA, K
    [J]. CARBON, 1989, 27 (02) : 253 - 257
  • [10] CARBONIZATION AND GRAPHITIZATION OF POLYIMIDE UPILEX
    INAGAKI, M
    SAKAMOTO, KI
    HISHIYAMA, Y
    [J]. JOURNAL OF MATERIALS RESEARCH, 1991, 6 (05) : 1108 - 1113
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