Kinetics of transesterification reaction of the sunflower oil

被引:0
作者
Stepan, Emil
Velea, Sanda
Enascuta, Cristina
Marton, George Iuliu
Gijiu, Cristiana Luminita
机构
[1] Inst Natl Cercetare Dezvoltare Pentru Chim Si Pet, ICECHIM, Bucharest, Romania
[2] Univ Politehn Bucuresti, Fac Chim Aplicata Si Stiinta Materialelor, Bucharest 011061, Romania
来源
REVISTA DE CHIMIE | 2006年 / 57卷 / 07期
关键词
kinetics; transesterification; sunflower oil; methyl esters; biodiesel; renewable fuels; mixing;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aim of the work was to investigate kinetics of sun flower oil with methyl alcohol (5,16 rapport molar methanol/oil) in the presence of potassium hydroxide (0, 4 % wt) at 4,12 and 20 degrees C The variations in mixing intensity (Re = 650, 920 and 1170) were determined by the change of the properties only (the impeller rotational speed 1000 rpm was constant). For a second order reaction proposed, the reaction velocity constants were found to be (l/s) 0, 00159; 0, 00223; 0, 00318 at 4, 12 and 20 degrees C, respectively. The value E = 6965 cal/mole is in the limits of activation energy for these reactions.
引用
收藏
页码:693 / 698
页数:6
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