Versatility of a Nitrogen-Containing Monolithic Porous Carbon for Lithium-Based Energy Storage

被引:3
|
作者
Tesio, Alvaro Y. [1 ]
Arias, Analia N. [2 ]
Morales, Julian [3 ]
Planes, Gabriel A. [1 ]
Caballero, Alvaro [3 ]
机构
[1] Univ Nacl Rio Cuarto, Dept Quim, Fac Ciencias Exactas Fis Quim & Nat, Ruta Nac 36 Km 601, Cordoba, Argentina
[2] Univ Nacl Jujuy, Ctr Invest & Desarrollo Mat Avanzados & Almacenam, CONICET, Ctr Desarrollo Tecnol Gen Savio, Papala, Jujuy, Argentina
[3] Univ Cordoba, Dept Quim Inorgan, Inst Univ Invest Quim Fina & Nanoquim, Campus Rabanales, E-14071 Cordoba, Spain
来源
CHEMISTRYSELECT | 2018年 / 3卷 / 29期
关键词
Energy storage; Lithium batteries; Monolithic Nitrogen-containing carbon; Sulfur cathodes; DOPED MESOPOROUS CARBON; OXYGEN REDUCTION REACTION; LI-S BATTERIES; CO2; CAPTURE; GRAPHENE; FORMALDEHYDE; PERFORMANCE; ELECTRODES; RESORCINOL; CATALYSTS;
D O I
10.1002/slct.201801330
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N-containing monolithic porous carbon material with dual micro and mesoporous structures was synthesized using an innovative, cheap and easy synthesis route based on the classical resorcinol-formaldehyde synthesis. A completely chemical, structural and morphological characterization was carried out. The N content in the carbonaceous material was 7.3% and XPS data showed that is present in two different surrounds, as N-pyrrolic and N-pyridinic atoms. Is known that, the last one, can acts as a catalyst at surface level in heterogeneous reactions. In addition, using this material, we were able to fabricate lithium-ion and lithium-sulfur batteries obtaining high values of discharge capacity and cycle stability and demonstrating the multifunctional character of this carbon in energy storage devices.
引用
收藏
页码:8560 / 8567
页数:8
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