Solubility of d-elements salts in organic and aqueous-organic solvents: I. Copper, cobalt, and cadmium sulfates

被引：11
作者：
Bogachev, N. A. [1 ]
Gorbunov, A. O. [1 ]
Tikhomirova, A. A. [1 ]
Pushikhina, O. S. [1 ]
Skripkin, M. Yu. [1 ]
Nikolskii, A. B. [1 ]
机构：
[1] St Petersburg State Univ, St Petersburg 199034, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 11期
基金：
俄罗斯基础研究基金会;
关键词：
solubility; sulfate; d-element; ternary system; ionic association; mixed solvent; DIMETHYL-SULFOXIDE; CHLORIDE COMPLEXES; WATER; SOLVATION; SYSTEMS; EQUILIBRIUM; ENTHALPIES; MIXTURES; ENERGIES; SOFTNESS;
D O I：
10.1134/S107036321511002X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solubility at 25A degrees C has been determined in the MSO4-H2O-Solv systems (M = Co, Cu, or Cd; Solv = dimethyl sulfoxide, dimethyl formamide, dimethyl acetamide, tetrahydrofuran, or dioxane) via the isothermal saturation method. Analysis of the solubility as function of the permittivity and donor power of solvents along with the information on the cations radius leads to the conclusion that ion-ion association dominates over solvation interactions in the studied systems.
引用
收藏
页码：2509 / 2512
页数：4
相关论文
共 8 条
  • [1] Solubility of d-elements salts in organic and aqueous-organic solvents: I. Copper, cobalt, and cadmium sulfates
    N. A. Bogachev
    A. O. Gorbunov
    A. A. Tikhomirova
    O. S. Pushikhina
    M. Yu. Skripkin
    A. B. Nikolskii
    Russian Journal of General Chemistry, 2015, 85 : 2509 - 2512
  • [2] Solubility of d-elements salts in organic and aqueous-organic solvents: IV. Solubility of cadmium chloride
    Bogachev, N. A.
    Tsyrulnikov, N. A.
    Gorbunov, A. O.
    Nikolskii, A. B.
    Skripkin, M. Yu.
    Burkov, K. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (11) : 2405 - 2409
  • [3] Solubility of d-elements salts in organic and aqueous-organic solvents: IV. Solubility of cadmium chloride
    N. A. Bogachev
    N. A. Tsyrulnikov
    A. O. Gorbunov
    A. B. Nikolskii
    M. Yu. Skripkin
    K. A. Burkov
    Russian Journal of General Chemistry, 2016, 86 : 2405 - 2409
  • [4] Solubility of d-elements salts in organic and aqueous-organic solvents: III. Influence of intermolecular association on solubility of cadmium bromide and iodide
    Bogachev, N. A.
    Gorbunov, A. O.
    Nikolskii, A. B.
    Skripkin, M. Yu.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (07) : 1539 - 1544
  • [5] Solubility of d-element salts in organic and aqueous-organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride
    Gorbunov, A. O.
    Tsyrul'nikov, N. A.
    Tikhomirova, A. A.
    Bogachev, N. A.
    Skripkin, M. Yu.
    Nikolskii, A. B.
    Pestova, O. N.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (04) : 771 - 777
  • [6] Solubility of d-element salts in organic and aqueous–organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride
    A. O. Gorbunov
    N. A. Tsyrul’nikov
    A. A. Tikhomirova
    N. A. Bogachev
    M. Yu. Skripkin
    A. B. Nikolskii
    O. N. Pestova
    Russian Journal of General Chemistry, 2016, 86 : 771 - 777
  • [7] Thermodynamics of the Acid-Base Equilibria of Glycyl-Glycyl-Glycine and the Formation of Its Complex with a Copper(II) Ion in Aqueous-Organic Solvents
    Usacheva, T. R.
    Pham Thi Lan
    Sharnin, V. A.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 93 (01) : 81 - 88
  • [8] Polyrotaxane derivatives. I. Preparation of modified polyrotaxanes with nonionic functional groups and their solubility in organic solvents
    Araki, Jun
    Ito, Kohzo
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (21) : 6312 - 6323
1