A comparative study of formaldehyde and carbon monoxide complete oxidation on MnOx-CeO2 catalysts

被引：74
|
作者：
Liu Xuesong [1 ]
Lu Jiqing [1 ]
Qian Kun [2 ,3 ]
Huang Weixin [2 ,3 ]
Luo Mengfei [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China
[2] Univ Sci & Technol China, Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
[3] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China
来源：
JOURNAL OF RARE EARTHS | 2009年 / 27卷 / 03期
关键词：
MnOx-CeO2; catalysts; complete oxidation; HCHO; CO; rare earths; CO OXIDATION; OXIDE CATALYST; MANGANESE OXIDES; TEMPERATURE; CERIA; COMBUSTION; REDUCTION; SURFACE; OXYGEN; MECHANISM;
D O I：
10.1016/S1002-0721(08)60263-X
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
MnOx-CeO2 composite catalysts were prepared by a coprecipitation method and tested for formaldehyde (HCHO) and carbon monoxide (CO) oxidation. X-ray photon spectroscopy (XPS) results indicated that the average oxidation state of surface Mn species in CeMn composite catalyst was higher compared to the pure MnOx. The enhancement of reactivity for HCHO oxidation was due to the activation of the lattice oxygen species in MnOx by the addition of CeO2, which was confirmed by the H-2 temperature programmed reduction (H-2-TPR) results. The remarkable enhancement of reactivity for CO oxidation by the addition of CeO2 was due to the active oxygen species generated on the CeO2 surface which directly participated in the reaction.
引用
收藏
页码：418 / 424
页数：7
相关论文
共 50 条
  • [1] A comparative study of formaldehyde and carbon monoxide complete oxidation on MnOx-CeO2 catalysts
    刘雪松
    鲁继青
    千坤
    黄伟新
    罗孟飞
    Journal of Rare Earths, 2009, 27 (03) : 418 - 424
  • [2] Complete oxidation of formaldehyde over Ag/MnOx-CeO2 catalysts
    Tang, XF
    Chen, JL
    Li, YG
    Li, Y
    Xu, YD
    Shen, WJ
    CHEMICAL ENGINEERING JOURNAL, 2006, 118 (1-2) : 119 - 125
  • [3] Complete oxidation of formaldehyde over Ag/MnOx-CeO2 catalysts
    Tang, Xingfu
    Chen, Junli
    Li, Yonggang
    Li, Yong
    Xu, Yide
    Shen, Wenjie
    Chemical Engineering Journal, 2006, 118 (1-2): : 119 - 125
  • [4] Pt/MnOx-CeO2 catalysts for the complete oxidation of formaldehyde at ambient temperature
    Tang, Xingfu
    Chen, Junli
    Huang, Xiumin
    Xu, Yide
    Shen, Wenjie
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 81 (1-2) : 115 - 121
  • [5] Study of Complete Oxidation of Formaldehyde Over MnOx-CeO2 Mixed Oxide Catalysts at Ambient Temperature
    Huang, Qiong
    Lu, Yueying
    Si, Han
    Yang, Bo
    Tao, Tao
    Zhao, Yunxia
    Chen, Mindong
    CATALYSIS LETTERS, 2018, 148 (09) : 2880 - 2890
  • [6] Catalytic Oxidation of Formaldehyde Over Mesoporous MnOx-CeO2 Catalysts
    Zhao, Yanlei
    Tian, Hua
    He, Junhui
    Yang, Qiaowen
    INTERNATIONAL JOURNAL OF NANOSCIENCE, 2015, 14 (1-2)
  • [7] MnOx-CeO2 mixed oxide catalysts for complete oxidation of formaldehyde:: Effect of preparation method and calcination temperature
    Tang, XF
    Li, YG
    Huang, XM
    Xu, YD
    Zhu, HQ
    Wang, JG
    Shen, WJ
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 62 (3-4) : 265 - 273
  • [8] Total Oxidation of Formaldehyde over MnOx-CeO2 Catalysts: The Effect of Acid Treatment
    Quiroz, Jhon
    Giraudon, Jean-Marc
    Gervasini, Antonella
    Dujardin, Christophe
    Lancelot, Christine
    Trentesaux, Martine
    Lamonier, Jean-Francois
    ACS CATALYSIS, 2015, 5 (04): : 2260 - 2269
  • [9] Intrinsic Activity of MnOx-CeO2 Catalysts in Ethanol Oxidation
    Delimaris, Dimitrios
    Ioannides, Theophilos
    CATALYSTS, 2017, 7 (11)
  • [10] Effect of preparation method on MnOx-CeO2 catalysts for NO oxidation
    崔明山
    李渊
    王欣全
    王军
    沈美庆
    JournalofRareEarths, 2013, 31 (06) : 572 - 576
12345