2,4,6-trimethyl-1,3,5-tris(2-pyrimidinyl-thiomethyl)benzene chloroform hemisolvate

被引：2
作者：
Zheng, Y
Li, JR
Xie, YB
Bu, XH [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S1600536802012680
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C24H24N6S3.0.5CHCl(3) (TPSB.0.5CHCl(3)), crystallizes with one molecule of TPSB and half a solvent molecule of CHCl3 in the asymmetric unit. The three 2-pyrimidinylthiomethyl groups attached to the central benzene ring adopt a cis,cis,cis conformation. The molecule of TPSB is analogous to a 'three-legged stool', and the dihedral angles between each of the three 'legs' (2-pyrimidinyl rings) and the central benzene ring are 87.0 (5), 78.2 (3) and 97.1 (6)degrees, respectively, while the angles between the three 'legs' are 41.1 (3), 91.3 (5) and 49.5 (7)degrees, respectively.
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页码：o923 / o924
页数：2
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