Nanostructured tin for use as a negative electrode material in Li-ion batteries

被引：123
|
作者：
Whitehead, AH [1 ]
Elliott, JM [1 ]
Owen, JR [1 ]
机构：
[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
来源：
JOURNAL OF POWER SOURCES | 1999年 / 81卷
关键词：
nanostructure; lithium; mesoporous; liquid crystal template; polyoxyethylene ether;
D O I：
10.1016/S0378-7753(99)00126-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of mesoporous tin samples have been prepared by means of a liquid crystal templating method. TEM images and X-ray diffraction data show the mesoporosity and the scale of the repeat structure. The lithium insertion and extraction behaviour of liquid crystal templated films were compared with those obtained from non-templating electrolytes. It was found that the templated films showed higher extraction capacities, which were attributed to the ability of mesoporous tin to expand and contract with less structural degradation than nonporous tin. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：33 / 38
页数：6
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