Effect of soil properties on pure and formulated mesotrione adsorption onto vertisol (Limagne plane, Puy-de-Dome, France)

被引：15
作者：
Alekseeva, Tatiana [1 ,2 ]
Kolyagin, Yury [3 ]
Sancelme, Martine [1 ]
Besse-Hoggan, Pascale [1 ]
机构：
[1] Univ Blaise Pascal, UMR CNRS 6296, ICCF, Univ Clermont Ferrand 2, F-63171 Aubiere, France
[2] Russian Acad Sci, Inst Phys Chem & Biol Problems Soil Sci, Pushchino 142292, Russia
[3] Lomonosov Univ, Fac Chem, Moscow, Russia
来源：
CHEMOSPHERE | 2014年 / 111卷
关键词：
Mesotrione; Callisto (R); Vertisol; Mineralogy; Organic matter; C-13 NMR spectroscopy; ORGANIC-MATTER; C-13; NMR; SORPTION; DEGRADATION; PESTICIDES; ATRAZINE;
D O I：
10.1016/j.chemosphere.2014.03.061
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The fate of ionisable pesticides in the environment is complex as it is importantly related to many soil properties: pH, mineralogy, organic matter content and other soil characteristics. The adsorption of a weak acid herbicide, mesotrione, was studied in detail on whole and peroxide-treated vertisol topsoil and also on its granulometric fractions (clay, silt, sand) to evaluate the role of mineralogy and different organic matter pools. The soil studied is alkaline silty loam with smectite as the main clay mineral. It contains 1.7% organic carbon, mostly stabilized as a complex with smectite. Humus is of fulvic type. Mesotrione adsorption occurs on both mineral and organic constituents. Adsorption is weak and mesotrione can be easily and totally desorbed. As shown with C-13 NMR experiments, adsorption best correlates with the alkyl and carboxylic carbon content, and occurs on both bound and free organic matter. No difference of mesotrione sorption was observed with the formulation Callisto(R). (C) 2014 Elsevier Ltd. All rights reserved.
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收藏
页码：177 / 183
页数：7
相关论文
共 29 条
[1]   Effect of earthworm activity (Aporrectodea giardi) on atrazine adsorption and biodegradation [J].
Alekseeva, T. . ;
Besse, P. ;
Binet, F. ;
Delort, A. M. ;
Forano, C. ;
Josselin, N. ;
Sancelme, M. ;
Tixier, C. .
EUROPEAN JOURNAL OF SOIL SCIENCE, 2006, 57 (03) :295-307
[2]   Fractionation of humic acids by clay minerals assayed by 13C-NMR spectroscopy [J].
Alekseeva T.V. ;
Zolotareva B.N. ;
Kolyagin Y.G. .
Doklady Biological Sciences, 2010, 434 (1) :341-346
[3]  
[Anonymous], 2003, Refuse Derived Fuel, current practice and perspectives, P1
[4]   The mobility and degradation of pesticides in soils and the pollution of groundwater resources [J].
Arias-Estevez, Manuel ;
Lopez-Periago, Eugenio ;
Martinez-Carballo, Elena ;
Simal-Gandara, Jesus ;
Mejuto, Juan-Carlos ;
Garcia-Rio, Luis .
AGRICULTURE ECOSYSTEMS & ENVIRONMENT, 2008, 123 (04) :247-260
[5]  
BALDOCK JA, 1992, BIOGEOCHEMISTRY, V16, P1, DOI 10.1007/BF02402261
[6]   Herbicidal 4-hydroxyphenylpyruvate dioxygenase inhibitors-A review of the triketone chemistry story from a Syngenta perspective [J].
Beaudegnies, Renaud ;
Edmunds, Andrew J. F. ;
Fraser, Torquil E. M. ;
Hall, Roger G. ;
Hawkes, Timothy R. ;
Mitchell, Glynn ;
Schaetzer, Juergen ;
Wendeborn, Sebastian ;
Wibley, Jane .
BIOORGANIC & MEDICINAL CHEMISTRY, 2009, 17 (12) :4134-4152
[7]   Atrazine biodegradation modulated by clays and clay/humic acid complexes [J].
Besse-Hoggan, Pascale ;
Alekseeva, Tatiana ;
Sancelme, Martine ;
Delort, Anne-Marie ;
Forano, Claude .
ENVIRONMENTAL POLLUTION, 2009, 157 (10) :2837-2844
[8]   MINERALOGICAL COMPOSITION OF THE CLAY FRACTION OF THE BLACK SOILS OF LIMAGNE - THE PROBLEM OF CLAY-ORGANIC MATTER COMPLEX [J].
BORNAND, M ;
DEJOU, J ;
ROBERT, M ;
ROGER, L .
AGRONOMIE, 1984, 4 (01) :47-61
[9]   Sorption of tebuconazole onto selected soil minerals and humic acids [J].
Cadkova, Eva ;
Komarek, Michael ;
Kaliszova, Regina ;
Koudelkova, Vera ;
Dvorak, Jiri ;
Vanek, Ales .
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES, 2012, 47 (04) :336-342
[10]   Behaviour of sulcotrione and mesotrione in two soils [J].
Chaabane, Hanene ;
Vulliet, Emmanuelle ;
Calvayrac, Christophe ;
Coste, Camille-Michel ;
Cooper, Jean-Francois .
PEST MANAGEMENT SCIENCE, 2008, 64 (01) :86-93
123