Dehydration of fructose and glucose to 5-hydroxymethylfurfural over Al-KCC-1 silica

被引：61

作者：

Shahangi, Fereshte ^{[1
]}

Chermahini, Alireza Najafi ^{[1
]}

Saraji, Mohammad ^{[1
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415483111, Iran

来源：

JOURNAL OF ENERGY CHEMISTRY | 2018年 / 27卷 / 03期

关键词：

Glucose; Fructose; HMF production; Al-KCC-1; Dehydration of carbohydrates; ORDERED MESOPOROUS SILICA; MUKAIYAMA ALDOL REACTION; SOLID ACID; EFFICIENT CONVERSION; CATALYTIC CONVERSION; 2,5-FURANDICARBOXYLIC ACID; SELECTIVE CONVERSION; DIMETHYL-SULFOXIDE; MCM-41; SILICA; IONIC LIQUIDS;

D O I：

10.1016/j.jechem.2017.06.004

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this research, the influence of several factors such as reaction time, catalyst weight, temperature and different solvents on dehydration reaction of fructose and glucose to 5-hydroxymethylfurfural (HMF) was surveyed. Nanosphere Al-KCC-1 silica with fibrous morphology was manufactured and used as proficient and recyclable catalyst for this reaction. SEM, TEM, BET, XRD, EDX, elemental mapping, ICP and FT-IR spectroscopy methods were applied for characterization of the Al-KCC-1 (molar ratio Si/Al = 5, 40) catalysts. 162 degrees C and 1 h are the best conditions for the fructose dehydration. Under this situation HMF yield and selectivity are 92.9% and 94.5% respectively and fructose conversion is 98.4%. Also 170 degrees C and 2 h are the best conditions for the glucose dehydration. In this situation HMF yield and selectivity are 39.0% and 39.9% respectively and glucose conversion is 97.8%. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

引用

页码：769 / 780

页数：12

共 66 条

[1] Enzymatic transesterification for production of biodiesel using yeast lipases: An overview [J].

Aarthy, M. ;

Saravanan, P. ;

Gowthaman, M. K. ;

Rose, C. ;

Kamini, N. R. .

CHEMICAL ENGINEERING RESEARCH & DESIGN, 2014, 92 (08) :1591-1601

[2] Iron complex immobilized catalyst based on β-ketiminate ligand: Alkene oxygenation activity depending on the morphology of silica support and the structures of base additives [J].

Akashi, Takahiro ;

Nakazawa, Jun ;

Hikichi, Shiro .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 371 :42-47

[3] Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals [J].

Antonakou, Eleni ;

Lappas, Angelos ;

Nilsen, Merete H. ;

Bouzga, Aud ;

Stocker, Michael .

FUEL, 2006, 85 (14-15) :2202-2212

[4] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[5] Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone [J].

Buntara, Teddy ;

Noel, Sebastien ;

Phua, Pim Huat ;

Melian-Cabrera, Ignacio ;

de Vries, Johannes G. ;

Heeres, Hero J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (31) :7083-7087

[6] Heterogeneous catalysts based on vanadyl phosphate for fructose dehydration to 5-hydroxymethyl-2-furaldehyde [J].

Carlini, C ;

Patrono, P ;

Galletti, AMR ;

Sbrana, G .

APPLIED CATALYSIS A-GENERAL, 2004, 275 (1-2) :111-118

[7] In situ synthesized Pd nanoparticles supported on B-MCM-41: an efficient catalyst for hydrogenation of nitroaromatics in supercritical carbon dioxide [J].

Chatterjee, Maya ;

Ishizaka, Takayuki ;

Suzuki, Toshishige ;

Suzuki, Akira ;

Kawanami, Hajime .

GREEN CHEMISTRY, 2012, 14 (12) :3415-3422

[8] Hydrocracking in Al-MCM-41: diffusion effect [J].

Chen, WH ;

Zhao, Q ;

Lin, HP ;

Yang, YS ;

Mou, CY ;

Liu, SB .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 66 (2-3) :209-218

[9] Conversion of chitin and N-acetyl-D-glucosamine into a N-containing furan derivative in ionic liquids [J].

Chen, Xi ;

Liu, Yi ;

Kerton, Francesca M. ;

Yan, Ning .

RSC ADVANCES, 2015, 5 (26) :20073-20080

[10] Production of 5-hydroxymethylfurfural from fructose using a spherically fibrous KCC-1 silica catalyst [J].

Chermahini, Alireza Najafi ;

Shahangi, Fereshte ;

Dabbagh, Hossein A. ;

Saraji, Mohammad .

RSC ADVANCES, 2016, 6 (40) :33804-33810

← 1 2 3 4 5 6 7 →