A review of electrolytes for lithium-sulphur batteries

被引：375

作者：

Scheers, Johan ^{[1
]}

Fantini, Sebastien ^{[2
]}

Johansson, Patrik ^{[1
,3
]}

机构：

[1] Chalmers Univ Technol, Dept Appl Phys, SE-41296 Gothenburg, Sweden

[2] Solvionic SA, FR-31078 Toulouse, France

[3] ALISTORE ERI European Res Inst, F-80039 Amiens, France

来源：

JOURNAL OF POWER SOURCES | 2014年 / 255卷

关键词：

Lithium-sulphur batteries; Electrolytes; Organic solvents; Ionic liquids; Lithium salts; COMPOSITE POLYMER ELECTROLYTES; GLYCOL) DIMETHYL ETHER; SULFONE-BASED ELECTROLYTES; IONIC LIQUID ELECTROLYTES; ELECTROCHEMICAL PROPERTIES; DISCHARGE PERFORMANCE; ELEMENTAL SULFUR; HIGH-CAPACITY; SOLID-ELECTROLYTE; CATHODE MATERIALS;

D O I：

10.1016/j.jpowsour.2014.01.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

To optimize the electrolyte is one of the most important directions to take in order to improve the Li/S battery in terms of performance - especially cell cyclability, rate capability, safety, and life-span. In this review we examine the state of the art for different choices of electrolytes; concepts, design, and materials, and how the resulting chemical and physical properties of the electrolyte affect the overall Li/S battery performance. The objective is to create an overall assessment of electrolytes in use at present and to provide a thorough basis for rational selection of future electrolytes for Li/S batteries. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：204 / 218

页数：15

共 157 条

[1] Sulfone-based electrolytes for high-voltage Li-ion batteries [J].

Abouimrane, A. ;

Belharouak, I. ;

Amine, K. .

ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (05) :1073-1076

[2] Highly conductive PEO-like polymer electrolytes [J].

Abraham, KM ;

Jiang, Z ;

Carroll, B .

CHEMISTRY OF MATERIALS, 1997, 9 (09) :1978-1988

[3] RUBBERY SOLID ELECTROLYTES WITH DOMINANT CATIONIC TRANSPORT AND HIGH AMBIENT CONDUCTIVITY [J].

ANGELL, CA ;

LIU, C ;

SANCHEZ, E .

NATURE, 1993, 362 (6416) :137-139

[4] THE HISTORY OF POLYMER ELECTROLYTES [J].

ARMAND, M .

SOLID STATE IONICS, 1994, 69 (3-4) :309-319

[5]

Armand M., 2011, Pentacyclic Anion Salt and Use Thereof as an Electrolyte, Patent No. [US 2011/0311884 Al, 20110311884]

[6]

Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]

[7] Battery separators [J].

Arora, P ;

Zhang, ZM .

CHEMICAL REVIEWS, 2004, 104 (10) :4419-4462

[8] On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries [J].

Aurbach, Doron ;

Pollak, Elad ;

Elazari, Ran ;

Salitra, Gregory ;

Kelley, C. Scordilis ;

Affinito, John .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (08) :A694-A702

[9] Electrochemical properties of ether-based electrolytes for lithium/sulfur rechargeable batteries [J].

Barchasz, Celine ;

Lepretre, Jean-Claude ;

Patoux, Sebastien ;

Alloin, Fannie .

ELECTROCHIMICA ACTA, 2013, 89 :737-743

[10] Revisiting TEGDME/DIOX Binary Electrolytes for Lithium/Sulfur Batteries: Importance of Solvation Ability and Additives [J].

Barchasz, Celine ;

Lepretre, Jean-Claude ;

Patoux, Sebastien ;

Alloin, Fannie .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (03) :A430-A436

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