Structure, magnetic and luminescence properties of the lanthanide complexes Ln2(Salphen)3•H2O (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy; H2Salphen = N,N'-bis(salicylidene)-1,2-phenylenediamine)

被引：30
作者：
Mikhalyova, Elena A. [1 ]
Yakovenko, Anastasiya V. [1 ]
Zeller, Matthias [2 ,3 ]
Gavrilenko, Konstantin S. [4 ]
Lofland, Samuel E. [5 ]
Addison, Anthony W. [6 ]
Pavlishchuk, Vitaly V. [1 ]
机构：
[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, UA-03028 Kiev, Ukraine
[2] Youngstown State Univ, STARBURSTT CyberInstrumentat Consortium, Youngstown, OH 44555 USA
[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
[4] Taras Shevchenko Natl Univ Kyiv, Chembioctr, UA-03022 Kiev, Ukraine
[5] Rowan Univ, Dept Phys & Astron, Glassboro, NJ 08028 USA
[6] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA
来源：
INORGANICA CHIMICA ACTA | 2014年 / 414卷
关键词：
Coordination compounds; Lanthanide complexes; Luminescence; Magnetic properties; METAL-ORGANIC FRAMEWORKS; SCHIFF-BASE COMPLEXES; COORDINATION POLYMERS; SOLID-STATE; CRYSTAL-STRUCTURE; THERMAL-BEHAVIOR; LIGANDS; DINUCLEAR; OXALATE; IONS;
D O I：
10.1016/j.ica.2014.01.034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The series of compounds Ln(2)(Salphen)(3)(H2O) (1-Ln; Ln = Pr, Nd, Sm, Eu, Gd, Tb and Dy) was obtained. The crystal structure of 1-Nd was determined, and its isomorphism with the others was shown by powder XRD. These compounds possess dinuclear molecules with Ln-Ln distances of 3.965(30) angstrom (for 1-Nd). A systematic analysis of the magnetic properties of the complexes 1-Ln was performed in terms of the temperature dependences of the magnetic susceptibilities, revealing weak or, in the cases of the Eu and Dy complexes, negligible exchange interactions between the lanthanide ions. Compound 1-Eu displays characteristic Eu3+ photoluminescence at 77 K both in the solid state and in DMF/MeOH solution. (C) 2014 Elsevier B. V. All rights reserved.
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页码：97 / 104
页数：8
相关论文
共 76 条
  • [41] Ln2(C2O4)2(pyzc)2(H2O)2]n [Ln = Pr (1), Er (2)]:: Novel two-dimensional lanthanide coordination polymers with 2-pyrazinecarboxylate and oxalate
    Li, Bing
    Gu, Wen
    Zhang, Li-Zhi
    Qu, Jie
    Ma, Zhen-Ping
    Liu, Xin
    Liao, Dai-Zheng
    [J]. INORGANIC CHEMISTRY, 2006, 45 (26) : 10425 - 10427
  • [42] An unsymmetrical coordination environment leading to two slow relaxation modes in a Dy2 single-molecule magnet
    Lin, Po-Heng
    Sun, Wen-Bin
    Yu, Mang-Fei
    Li, Guang-Ming
    Yan, Peng-Fei
    Murugesu, Muralee
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (39) : 10993 - 10995
  • [43] Fluorescent dialdehyde ligand for the encapsulation of dinuclear luminescent lanthanide complexes
    Lin, Po-Heng
    leclere, Mathieu
    Long, Jerome
    Burchell, Tara J.
    Korobkov, Ilia
    Clerac, Rodolphe
    Murugesu, Muralee
    [J]. DALTON TRANSACTIONS, 2010, 39 (24) : 5698 - 5704
  • [44] Lanthanides in molecular magnetism: so fascinating, so challenging
    Luzon, Javier
    Sessoli, Roberta
    [J]. DALTON TRANSACTIONS, 2012, 41 (44) : 13556 - 13567
  • [45] Synthesis, structure and magnetic properties of Nd3+ and Pr3+ 2D polymers with tetrafluoro-p-phthalate
    Mikhalyova, Elena A.
    Kolotilov, Sergey V.
    Zeller, Matthias
    Thompson, Laurence K.
    Addison, Anthony W.
    Pavlishchuk, Vitaly V.
    Hunter, Allen D.
    [J]. DALTON TRANSACTIONS, 2011, 40 (41) : 10989 - 10996
  • [46] Miller J. S., 2005, MAGNETISM MOL MAT, VV
  • [47] A rare one-dimensional Dy(III) complex exhibiting slow magnetic relaxation
    Na, Bo
    Wang, Yu-Xia
    Han, Tian
    Shi, Wei
    Cheng, Peng
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 35 : 19 - 21
  • [48] A series of three-dimensional lanthanide MOFs: Observation of reversible structural changes controlled by solvent desorption-adsorption, and magnetic properties
    Nayak, Sanjit
    Nayek, Hari Pada
    Pietzonka, Clemens
    Novitchi, Ghenadie
    Dehnen, Stefanie
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2011, 1004 (1-3) : 82 - 87
  • [49] SYNTHESIS AND SPECTRAL PROPERTIES OF THE EUROPIUM(III) CHELATES WITH SCHIFF-BASES
    NOWICKI, W
    ZACHARA, S
    [J]. SPECTROSCOPY LETTERS, 1992, 25 (04) : 593 - 601
  • [50] Three-dimensional 3d-4f polymers containing heterometallic rings: Syntheses, structures, and magnetic properties
    Ouyang, Yan
    Zhang, Wei
    Xu, Na
    Xu, Gong-Feng
    Liao, Dai-Zheng
    Yoshimura, Kazuyoshi
    Yan, Shi-Ping
    Cheng, Peng
    [J]. INORGANIC CHEMISTRY, 2007, 46 (21) : 8454 - 8456
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