The cation as a tool to get spin-canted three-dimensional iron(III) networks

被引：31
作者：
Armentano, D
De Munno, G [1 ]
Mastropietro, TF
Proserpio, DM
Julve, M
Lloret, F
机构：
[1] Univ Calabria, Dipartimento Chim, I-87030 Arcavacata Di Rende, Italy
[2] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-21033 Milan, Italy
[3] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, E-46100 Valencia, Spain
来源：
INORGANIC CHEMISTRY | 2004年 / 43卷 / 17期
关键词：
D O I：
10.1021/ic049345z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at T-c values ranging from 40 to 56 K. The value of T-c varies with the cation despite the lack of significant structural modifications.
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页码：5177 / 5179
页数：3
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