Room temperature methoxylation in zeolites: insight into a key step of the methanol-to-hydrocarbons process

被引：64

作者：

O'Malley, Alexander J. ^{[1
,2
]}

Parker, Stewart F. ^{[2
,3
]}

Chutia, Arunabhiram ^{[2
]}

Farrow, Matthew R. ^{[1
]}

Silverwood, Ian P. ^{[3
]}

Garcia-Sakai, Victoria ^{[3
]}

Catlow, C. Richard A. ^{[1
,2
,4
]}

机构：

[1] UCL, Dept Chem, Mat Chem, Third Floor,Kathleen Lonsdale Bldg,Gower St, London WC1E 6BT, England

[2] Rutherford Appleton Lab, UK Catalysis Hub, Res Complex Harwell, Oxford OX11 0FA, Oxon, England

[3] Rutherford Appleton Lab, STFC, ISIS Facil, Didcot OX11 0QX, Oxon, England

[4] Cardiff Univ, Sch Chem, Cardiff Catalysis Inst, Cardiff CF10 3AT, S Glam, Wales

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 14期

基金：

英国工程与自然科学研究理事会;

关键词：

FUNCTIONAL THEORY CALCULATIONS; MOLECULAR-DYNAMICS SIMULATION; ELASTIC NEUTRON-SCATTERING; DIMETHYL ETHER FORMATION; STATE NMR-SPECTROSCOPY; SURFACE METHOXY; EXTRAFRAMEWORK DEBRIS; BRONSTED ACIDITY; BOND FORMATION; OLEFIN PROCESS;

D O I：

10.1039/c5cc08956e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neutron scattering methods observed complete room temperature conversion of methanol to framework methoxy in a commercial sample of methanol-to-hydrocarbons (MTH) catalyst H-ZSM-5, evidenced by methanol immobility and vibrational spectra matched by ab initio calculations. No methoxylation was observed in a commercial HY sample, attributed to the dealumination involved in high silica HY synthesis.

引用

页码：2897 / 2900

页数：4

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