Crystallization of poly(ε-caprolactone)-block-polystyrene copolymers from glassy microdomain structures

被引：10
|
作者：
Nojima, S [1 ]
Kakihira, H
Tanimoto, S
Nakatani, H
Sasaki, S
机构：
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan
[2] Japan Adv Inst Sci & Technol, Ctr New Mat, Tatsunokuchi, Ishikawa 9231292, Japan
来源：
POLYMER JOURNAL | 2000年 / 32卷 / 01期
关键词：
crystalline-amorphous diblock copolymer; microdomain structure; glass transition; crystallization;
D O I：
10.1295/polymj.32.75
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The microdomain structure of poly(ε-caprolactone)-block-polystyrene (PCL-b-PS) in the melt was characterized by small angle X-ray scattering. The morphology formed in PCL-b-PS by the crystallization of PCL blocks was dependent on crystallization temperature. The glass transition of the amorphous domain affected significantly the difference in the morphology formation.
引用
收藏
页码：75 / 78
页数：4
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