Competitive diffusion and adsorption in Vycor glass membranes -: A lumped parameter approach

被引：16

作者：

Schluender, E. -U.

Yang, J.

Seidel-Morgenstern, A. ^{[1
]}

机构：

[1] Max Planck Inst Dynam Complex Tech Syst, D-39106 Magdeburg, Germany

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[3] Otto Von Guericke Univ, D-39106 Magdeburg, Germany

来源：

CATALYSIS TODAY | 2006年 / 118卷 / 1-2期

关键词：

Vycor glass membrane; Langmuir adsorption isotherm; Knudsen diffusion;

D O I：

10.1016/j.cattod.2005.11.094

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The interaction of simultaneous diffusion and adsorption of pure gases and gas mixtures in a Vycor glass membrane has been studied under transient conditions in a modified Wicke-Kallenbach cell. A lumped two parameter approach was developed in order to analyse all the observed pressure responses in a unified manner. This approach was found to be capable to fit well almost all the observations made for different types of gases and at different temperatures with sufficient or excellent accuracy. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：113 / 120

页数：8

共 12 条

[1]

Breck D.W, 1974, ZEOLITE MOL SIEVES

[2] Surface diffusion and adsorption of hydrocarbons in activated carbon [J].