Hydrogen production by the hydrolysis of milled waste magnesium scraps in nickel chloride solutions and nickel chloride added in Marmara Sea and Aegean Sea Water

被引：33

作者：

Figen, Aysel Kanturk ^{[1
]}

Filiz, Bilge Coskuner ^{[1
]}

机构：

[1] Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2015年 / 40卷 / 46期

关键词：

Hydrogen production; Magnesium scraps; Hydrolysis; Sea water; Nickel chloride; ALLOY SCRAPS; GENERATION; ALUMINUM; CORROSION; COMPOSITE; HYDRIDES; ACID; NACL;

D O I：

10.1016/j.ijhydene.2015.07.170

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The present study reports experimental results the effectivity of hydrogen production by the hydrolysis of milled waste magnesium scraps (MWMS) in nickel chloride (NiCl2) solutions (0.5 M-2.5 M) and NiCl2 added in Marmara Sea and Aegean Sea water. A micro-batch reactor is considered as hydrogen evolution reaction in solutions with variety of conductivity. The experimental results concern about hydrogen generation tests in presence of aqueous NiCl2 solutions, NiCl2 added in Marmara Sea and Aegean Sea water and also investigation of hydrogen generation kinetics at different temperatures (22 degrees C-60 degrees C). 2.5 M NiCl2 solution shows excellent MWMS conversion and hydrogen generation performance. Addition of 2.5 M NiCl2 into Marmara and Aegean Sea water has superficial effect on the conductivity and pH of solution and, MWMS conversion. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：16169 / 16177

页数：9

共 33 条

[1]

ANDREASEN A, 2005, PROPERTIES MG AL ALL

[2] Evaluation of a new hydrogen generating system: Ni-rich magnesium alloy catalyzed by platinum wire in sodium chloride solution [J].

Cho, CY ;

Wang, KH ;

Uan, JY .

MATERIALS TRANSACTIONS, 2005, 46 (12) :2704-2708

[3] Study of hydrogen production and storage based on aluminum-water reaction [J].

Elitzur, Shani ;

Rosenband, Valery ;

Gany, Alon .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (12) :6328-6334

[4] Recycling of magnesium drive train components [J].

Fechner, Daniel ;

Blawert, Carsten ;

Hort, Norbert ;

Kainer, Karl Ulrich .

SCIENCE IN CHINA SERIES E-TECHNOLOGICAL SCIENCES, 2009, 52 (01) :148-154

[5] Hydrogen generation from waste Mg based material in various saline solutions (NiCl2, CoCl2, CuCl2, FeCl3, MnCl2) [J].

Figen, Aysel Kanturk ;

Coskuner, Bilge ;

Piskin, Sabriye .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (24) :7483-7489

[6] Characterization and modification of waste magnesium chip utilized as an Mg-rich intermetallic composite [J].

Figen, Aysel Kanturk ;

Piskin, Sabriye .

PARTICUOLOGY, 2014, 17 :158-164

[7]

Fogler H. S, 1999, Elements of Chemical Reaction Engineering, V3rd

[8] Hydrogen production from highly corroding Mg-based materials elaborated by ball milling [J].

Grosjean, MH ;

Zidoune, M ;

Roué, L .

JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 404 :712-715

[9] Hydrogen production via hydrolysis reaction from ball-milled Mg-based materials [J].

Grosjean, MH ;

Zidoune, M ;

Roué, L ;

Huot, JY .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (01) :109-119

[10] Effect of ball milling on the corrosion resistance of magnesium in aqueous media [J].

Grosjean, MH ;

Zidoune, M ;

Roué, L ;

Huot, J ;

Schulz, R .

ELECTROCHIMICA ACTA, 2004, 49 (15) :2461-2470

← 1 2 3 4 →