Studies of the Interaction of Ionic Liquid and Gas in a Small-Diameter Bubble Column

被引:19
作者
Kaji, R. [1 ]
Zhao, D. [1 ]
Licence, P. [1 ]
Azzopardi, B. J. [1 ]
机构
[1] Univ Nottingham, Sch Chem & Environm Engn, Nottingham NG7 2RD, England
基金
英国工程与自然科学研究理事会;
关键词
HOLD-UP; NEWTONIAN LIQUIDS; REGIME TRANSITION; FLOW STRUCTURE; TAYLOR BUBBLE; CATALYSIS; VELOCITY; PRESSURE; SOLVENTS; REACTORS;
D O I
10.1021/ie8014439
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Gas bubbling through a column of ionic liquid has been investigated using high-speed video and a conductivity method to measure a cross-sectionally averaged void fraction. For comparison, other liquids with similar physical properties, e.g., a glycerol/water mixture and glycerol/water with dissolved potassium chloride, were also employed. Air was used for the gas phase. The similarities and differences of flow characteristics were observed from the images. The differences in flow patterns were revealed by analysis of the time series of conductance signals in the form of the probability density function, autocorrelation, and power spectrum density. Furthermore, the velocities and frequencies of flow structures were deduced. The flow characteristics of ionic liquid were found to be similar to those of the other liquids studied.
引用
收藏
页码:7938 / 7944
页数:7
相关论文
共 49 条
  • [1] [Anonymous], 1978, BUBBLES DROPS PARTIC
  • [2] [Anonymous], 1994, Patent US, Patent No. [5315019A, 5315019, 5 315 019]
  • [3] Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures
    Antonietti, M
    Kuang, DB
    Smarsly, B
    Yong, Z
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) : 4988 - 4992
  • [4] Measurement and analysis of flows in a gas-liquid column reactor
    Bennett, MA
    West, RM
    Luke, SP
    Jia, X
    Williams, RA
    [J]. CHEMICAL ENGINEERING SCIENCE, 1999, 54 (21) : 5003 - 5012
  • [5] Acoustic emission measurement of low velocity plunging jets to monitor bubble size
    Boyd, JWR
    Varley, J
    [J]. CHEMICAL ENGINEERING JOURNAL, 2004, 97 (01) : 11 - 25
  • [6] FLOW STRUCTURE IN A 3-DIMENSIONAL BUBBLE-COLUMN AND 3-PHASE FLUIDIZED-BED
    CHEN, RC
    REESE, J
    FAN, LS
    [J]. AICHE JOURNAL, 1994, 40 (07) : 1093 - 1104
  • [7] Ionic liquids: solvent properties and organic reactivity
    Chiappe, C
    Pieraccini, D
    [J]. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2005, 18 (04) : 275 - 297
  • [8] Cole-Hamilton D.J., 2006, Catalyst Separation, Recovery and Recycling: Chemistry and Process Design
  • [9] Homogeneous catalysis - new approaches to catalyst separation, recovery, and recycling
    Cole-Hamilton, DJ
    [J]. SCIENCE, 2003, 299 (5613) : 1702 - 1706
  • [10] Cornils B, 2005, MULTIPHASE HOMOGENEOUS CATALYSIS, VOLS 1 AND 2, P1, DOI 10.1002/9783527619597