Synthesis of poly(vinyl alcohol)/reduced graphite oxide nanocomposites with improved thermal and electrical properties

被引：281

作者：

Javier Salavagione, Horacio ^{[1
]}

Martinez, Gerardo ^{[1
]}

Gomez, Marian A. ^{[1
]}

机构：

[1] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2009年 / 19卷 / 28期

关键词：

CARBON NANOTUBES; LOAD-TRANSFER; COMPOSITE; REINFORCEMENT; POLYMERS; CONDUCTIVITY; DISSOLUTION; FABRICATION; NANOSHEETS; MECHANISM;

D O I：

10.1039/b904232f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Poly(vinylalcohol)/reduced graphite oxide nanocomposites have been synthesised by reducing graphite oxide in the presence of the polymer matrix and coagulating the system with 2-propanol. It has been observed that some interactions occur between the polymer and the reduced graphite oxide layers, mainly by hydrogen bonding. These interactions are responsible for a remarkable change in the thermal behaviour of the nanocomposites. In addition, high electrical conductivity has been achieved at concentrations beyond 7.5 wt% of reduced graphite oxide (similar to 0.1 S cm(-1)), with a percolation threshold between 0.5 and 1 wt%.

引用

页码：5027 / 5032

页数：6

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