Chemoselective epoxidation of dienes using polymer-supported manganese porphyrin catalysts

被引：55

作者：

Brulé, E

de Miguel, YR

Hii, KK ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Kings Coll London, Dept Chem, London WC2R 2LS, England

[3] LABEIN Technol Ctr, Bizkaia, Spain

来源：

TETRAHEDRON | 2004年 / 60卷 / 28期

关键词：

manganese porphyrins; alkene epoxidation; chemoselectivity; polymer-supported catalysis;

D O I：

10.1016/j.tet.2004.05.026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Manganese porphyrin catalysts supported on different polymer resins were assessed in the selective epoxidation of three dienes. The recyclability of the catalysts was examined. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：5913 / 5918

页数：6

共 11 条

[1] Dendrimer-metalloporphyrins: Synthesis and catalysis [J].

Bhyrappa, P ;

Young, JK ;

Moore, JS ;

Suslick, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (24) :5708-5711

[2] Supported manganese porphyrin catalysts as P450 enzyme mimics for alkene epoxidation [J].

Brulé, E ;

de Miguel, YR .

TETRAHEDRON LETTERS, 2002, 43 (47) :8555-8558

[3] Synthesis of threo- and erythro-bis(2,2′-tetrahydrofuran).: A novel serendipitous synthesis of a spiroketal [J].

Kelly, DR ;

Nally, J .

TETRAHEDRON LETTERS, 1999, 40 (11) :2209-2212

[4] TRANSITION-METAL PHTHALOCYANINS AS CATALYSTS FOR ALKENE EPOXIDATION [J].

LARSEN, E ;

JORGENSEN, KA .

ACTA CHEMICA SCANDINAVICA, 1989, 43 (03) :259-263

[5] HIGHLY OXIDATION RESISTANT INORGANIC-PORPHYRIN ANALOG POLYOXOMETALATE OXIDATION CATALYSTS .2. CATALYSIS OF OLEFIN EPOXIDATION AND ALIPHATIC AND AROMATIC HYDROXYLATIONS STARTING FROM ALPHA-2-P2W17O61(MN+.BR)(N-11) (MN+ = MN3+, FE3+, CO2+, NI2+, CU2+), INCLUDING QUANTITATIVE COMPARISONS TO METALLOPORPHYRIN CATALYSTS [J].

MANSUY, D ;

BARTOLI, JF ;

BATTIONI, P ;

LYON, DK ;

FINKE, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) :7222-7226

[6] Microwave-expedited olefin epoxidation over hydrotalcites using hydrogen peroxide and acetonitrile [J].

Pillai, UR ;

Sahle-Demessie, E ;

Varma, RS .

TETRAHEDRON LETTERS, 2002, 43 (16) :2909-2911

[7] BIOSYNTHETIC-STUDIES OF MARINE LIPIDS .11. SYNTHESIS, BIOSYNTHESIS, AND ABSOLUTE-CONFIGURATION OF THE INTERNALLY BRANCHED DEMOSPONGIC ACID, 22-METHYL-5,9-OCTACOSADIENOIC ACID [J].

RAEDERSTORFF, D ;

SHU, AYL ;

THOMPSON, JE ;

DJERASSI, C .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (12) :2337-2346

[8]

Tangestaninejad S, 2001, J CHEM RES, P444

[9]

Tayebee R, 2002, INDIAN J CHEM B, V41, P2190

[10] POLYMERIZATION OF PROPYLENE-OXIDE CATALYZED BY FIXED ALUMINUM PORPHYRIN [J].

UNO, H ;

TAKATA, K ;

MIZUTANI, Y .

REACTIVE POLYMERS, 1991, 15 :121-129

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