Immobilized ruthenium catalyst for carbon dioxide hydrogenation

被引:0
作者
Yu, Ying Min
Fei, Jin Hua
Zhang, Yi Ping
Zheng, Xiao Ming [1 ]
机构
[1] Zhejiang Univ, Inst Catalysis, Hangzhou 310028, Peoples R China
[2] Zhejiang Educ Inst, Dept Chem, Hangzhou 310012, Peoples R China
关键词
immobilization; resin; supported Ru catalyst; hydrogenation; CO2-expanded solvent;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three kinds of cross linked polystyrene resin (PS) supported ruthenium complexes were developed as catalysts for the synthesis of formic acid from carbon dioxide hydrogenation. Many factors, such as the functionalized supports, solvents and ligands, could influence their activities and reuse performances greatly. These immobilized catalysts also offer the industrial advantages such as easy separation.
引用
收藏
页码:1097 / 1100
页数:4
相关论文
共 10 条
[1]   Kinetic experiments and modeling of a three-phase catalytic hydrogenation reaction in supercritical CO2 [J].
Devetta, L ;
Giovanzana, A ;
Canu, P ;
Bertucco, A ;
Minder, BJ .
CATALYSIS TODAY, 1999, 48 (1-4) :337-345
[2]   HOMOGENEOUS HYDROGENATION OF CARBON-DIOXIDE [J].
JESSOP, PG ;
IKARIYA, T ;
NOYORI, R .
CHEMICAL REVIEWS, 1995, 95 (02) :259-272
[3]   Homogeneous catalysis in supercritical fluids [J].
Jessop, PG ;
Ikariya, T ;
Noyori, R .
CHEMICAL REVIEWS, 1999, 99 (02) :475-493
[4]  
KERLER B, 2004, APPL CATAL B-ENVIRON, V49, P120
[5]   Silica hybrid gel catalysts containing Group(VIII) transition metal complexes: Preparation, structural, and catalytic properties in the synthesis of N,N-dimethylformamide and methyl formate from supercritical carbon dioxide [J].
Krocher, O ;
Koppel, RA ;
Froba, M ;
Baiker, A .
JOURNAL OF CATALYSIS, 1998, 178 (01) :284-298
[6]   ACTIVATION OF CARBON-DIOXIDE .4. RHODIUM-CATALYZES HYDROGENATION OF CARBON-DIOXIDE TO FORMIC-ACID [J].
LEITNER, W ;
DINJUS, E ;
GASSNER, F .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 475 (1-2) :257-266
[7]   Ruthenium(II)-catalyzed hydrogenation of carbon dioxide to formic acid. theoretical study of real catalyst, ligand effects, and solvation effects [J].
Ohnishi, YY ;
Matsunaga, T ;
Nakao, Y ;
Sato, H ;
Sakaki, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (11) :4021-4032
[8]   A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H2 and diethylamine [J].
Schmid, L ;
Rohr, M ;
Baiker, A .
CHEMICAL COMMUNICATIONS, 1999, (22) :2303-2304
[9]   Environmentally benign multiphase catalysis with dense phase carbon dioxide [J].
Subramaniam, B ;
Lyon, CJ ;
Arunajatesan, V .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 37 (04) :279-292
[10]   Phase equilibrium for the hydrogenation of polystyrene in CO2-swollen solvents [J].
Xu, DW ;
Carbonell, RG ;
Roberts, GW ;
Kiserow, DJ .
JOURNAL OF SUPERCRITICAL FLUIDS, 2005, 34 (01) :1-9