Improving the esterification activity of Pseudomonas fluorescens and Burkholderia cepacia lipases via cross-linked cyclodextrin immobilization

被引:4
作者
Junior, Ivaldo I. [1 ]
Gaudino, Emanuela Calcio [2 ]
Martina, Katia [2 ]
Cravotto, Giancarlo [2 ]
Luque, Rafael
de Souza, Rodrigo O. M. A. [1 ]
机构
[1] Univ Fed Rio de Janeiro, Dept Quim Organ, BR-21941 Rio De Janeiro, Brazil
[2] Univ Turin, Dipartimento Sci & Tecnol Farm, I-10125 Turin, Italy
来源
RSC ADVANCES | 2014年 / 4卷 / 86期
关键词
FATTY-ACIDS; MONOACYLGLYCEROL; BIOCATALYSTS; CHEMISTRY; CATALYSTS; POLYMERS; SUPPORTS; GLYCEROL; BEHAVIOR; ENZYMES;
D O I
10.1039/c4ra03797a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The search for a new, efficient and sustainable matrix for biocatalyst immobilization is a growing area in biotechnology. Our proposed approach deals with the utilization of solid cross-linked beta-cyclodextrin as supports for enzyme immobilization. Results obtained in terms of enzyme activity and thermal stability of novel immobilised materials have been found to remarkably improve those obtained using commercial immobilized enzymes in esterification reactions (e.g., monostearin synthesis).
引用
收藏
页码:45772 / 45777
页数:6
相关论文
共 39 条
  • [11] Ultrasound-Promoted Copper-Catalyzed Azide-Alkyne Cycloaddition
    Cravotto, Giancarlo
    Fokin, Valery V.
    Garella, Davide
    Binello, Arianna
    Boffa, Luisa
    Barge, Alessandro
    [J]. JOURNAL OF COMBINATORIAL CHEMISTRY, 2010, 12 (01): : 13 - 15
  • [12] Evidence of RNAi in humans from systemically administered siRNA via targeted nanoparticles
    Davis, Mark E.
    Zuckerman, Jonathan E.
    Choi, Chung Hang J.
    Seligson, David
    Tolcher, Anthony
    Alabi, Christopher A.
    Yen, Yun
    Heidel, Jeremy D.
    Ribas, Antoni
    [J]. NATURE, 2010, 464 (7291) : 1067 - U140
  • [13] Enzymatic activity studies of Pseudomonas cepacia lipase adsorbed onto copolymer supports containing β-cyclodextrin
    Dhake, Kishor P.
    Karoyo, Abdalla H.
    Mohamed, Mohamed H.
    Wilson, Lee D.
    Bhanage, Bhalchandra M.
    [J]. JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2013, 87 : 105 - 112
  • [14] Artificial enzymes based on supramolecular scaffolds
    Dong, Zeyuan
    Luo, Quan
    Liu, Junqiu
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (23) : 7890 - 7908
  • [15] Designing Inorganic Porous Materials for Enzyme Adsorption and Applications in Biocatalysis
    Fried, Dorothee I.
    Brieler, Felix J.
    Froeba, Michael
    [J]. CHEMCATCHEM, 2013, 5 (04) : 862 - 884
  • [16] Heterogeneous catalytic synthesis using microreactor technology
    Frost, Christopher G.
    Mutton, Lynsey
    [J]. GREEN CHEMISTRY, 2010, 12 (10) : 1687 - 1703
  • [17] The utility of cyclodextrins in lipase-catalyzed transesterification in organic solvents: enhanced reaction rate and enantioselectivity
    Ghanem, A
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (08) : 1282 - 1291
  • [18] DoE oriented reaction optimization on the lipase-catalyzed monostearin synthesis
    Junior, Ivaldo I.
    Sutili, Felipe K.
    Leite, Selma G. F.
    Miranda, Leandro S. de M.
    Leal, Ivana C. R.
    de Souza, Rodrigo O. M. A.
    [J]. JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2011, 72 (3-4) : 313 - 318
  • [19] Study of the effect of DATEM.: 1.: Influence of fatty acid chain length on rheology and baking
    Köhler, P
    Grosch, W
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1999, 47 (05) : 1863 - 1869
  • [20] Esterification of fatty acids with glycerol over Fe-Zn double-metal cyanide catalyst
    Kotwal, Mehejabeen
    Deshpande, S. S.
    Srinivas, D.
    [J]. CATALYSIS COMMUNICATIONS, 2011, 12 (14) : 1302 - 1306