NiCo2O4 nanosheets grown on interconnected honeycomb-like porous biomass carbon for high performance asymmetric supercapacitors

被引:65
作者
Guo, Dongxuan [1 ]
Zhang, Li [1 ]
Song, Xiumei [2 ]
Tan, Lichao [1 ,3 ]
Ma, Huiyuan [1 ]
Jiao, Jia [1 ]
Zhu, Di [1 ]
Li, Fengbo [1 ]
机构
[1] Harbin Univ Sci & Technol, Coll Chem & Environm Engn, Coll Heilongjiang Prov, Key Lab Green Chem Engn & Technol, Harbin 150040, Heilongjiang, Peoples R China
[2] Harbin Inst Technol, State Key Lab Urban Water Resource & Environm, Harbin 150090, Heilongjiang, Peoples R China
[3] Harbin Engn Univ, Minist Educ, Key Lab Superlight Mat & Surface Technol, Harbin 150001, Heilongjiang, Peoples R China
基金
中国博士后科学基金;
关键词
ELECTROCHEMICAL ENERGY-STORAGE; SOLID-STATE SUPERCAPACITOR; ELECTRODE MATERIALS; ANODE MATERIAL; SURFACE-AREA; POMELO PEEL; GRAPHENE; ARRAYS; NANOSPHERES; CAPACITORS;
D O I
10.1039/c8nj00515j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, NiCo2O4 nanosheets grown on interconnected honeycomb-like porous biomass carbon (HLPBC) have been successfully fabricated by carbonization combined with a facile hydrothermal process. Benefiting from the unique structure and reasonable pore size/pore size distribution, the as-obtained composite (HLPBC (0.1 g)/NiCo2O4) exhibits satisfactory capacitive behavior (1137.5 F g(-1) at a current density of 5 A g(-1)) and an excellent cycling stability of 90.3% capacitance retention over continuous 5000 cycles. The HLPBC served as a scaffold to support the NiCo2O4 nanosheets. At the same time, it provides a pathway for transporting electrons with high speed. An asymmetric supercapacitor is fabricated using HLPBC/NiCo2O4 and activated carbon (AC) as positive and negative electrodes, respectively. The asymmetric supercapacitor can deliver a high energy density of 30.75 W h kg(-1) at a power density of 900 W kg(-1). These results suggest that HLPBC/NiCo2O4 can be a potential candidate for electrochemical energy storage devices.
引用
收藏
页码:8478 / 8484
页数:7
相关论文
共 41 条
[1]   Sustainable AC/AC hybrid electrochemical capacitors in aqueous electrolyte approaching the performance of organic systems [J].
Abbas, Qamar ;
Babuchowska, Paulina ;
Frckowiak, Elzbieta ;
Beguin, Francois .
JOURNAL OF POWER SOURCES, 2016, 326 :652-659
[2]   Fabrication of NiCO2O4 nanofibers by electrospinning [J].
Guan, HY ;
Shao, CL ;
Liu, YC ;
Yu, N ;
Yang, XH .
SOLID STATE COMMUNICATIONS, 2004, 131 (02) :107-109
[3]   Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode [J].
Hao, Pin ;
Zhao, Zhenhuan ;
Tian, Jian ;
Li, Haidong ;
Sang, Yuanhua ;
Yu, Guangwei ;
Cai, Huaqiang ;
Liu, Hong ;
Wong, C. P. ;
Umar, Ahmad .
NANOSCALE, 2014, 6 (20) :12120-12129
[4]   Preparation and performance of NiCo2O4 nanowires-loaded graphene as supercapacitor material [J].
He, Guangyu ;
Wang, Lin ;
Chen, Haiqun ;
Sun, Xiaoqiang ;
Wang, Xin .
MATERIALS LETTERS, 2013, 98 :164-167
[5]   Single-crystal ZnO nanorod/amorphous and nanoporous metal oxide shell composites: Controllable electrochemical synthesis and enhanced supercapacitor performances [J].
He, Yun-Bo ;
Li, Gao-Ren ;
Wang, Zi-Long ;
Su, Cheng-Yong ;
Tong, Ye-Xiang .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (04) :1288-1292
[6]   Characterisation of activated nanoporous carbon for supercapacitor electrode materials [J].
Janes, Alar ;
Kurig, Heisi ;
Lust, Enn .
CARBON, 2007, 45 (06) :1226-1233
[7]   Gold nanoparticle-enabled biological and chemical detection and analysis [J].
Jans, Hilde ;
Huo, Qun .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (07) :2849-2866
[8]   3D carbon based nanostructures for advanced supercapacitors [J].
Jiang, Hao ;
Lee, Pooi See ;
Li, Chunzhong .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (01) :41-53
[9]   Three-Dimensional NiCo2O4@Polypyrrole Coaxial Nanowire Arrays on Carbon Textiles for High-Performance Flexible Asymmetric Solid-State Supercapacitor [J].
Kong, Dezhi ;
Ren, Weina ;
Cheng, Chuanwei ;
Wang, Ye ;
Huang, Zhixiang ;
Yang, Hui Ying .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (38) :21334-21346
[10]   Tunable synthesis of hierarchical NiCo2O4 nanosheets-decorated Cu/CuOx nanowires architectures for asymmetric electrochemical capacitors [J].
Kuang, Min ;
Zhang, Yu Xin ;
Li, Tong Tao ;
Li, Kai Feng ;
Zhang, Sheng Mao ;
Li, Gang ;
Zhang, Wei .
JOURNAL OF POWER SOURCES, 2015, 283 :270-278