Clean synthesis of adipic acid by direct oxidation of cyclohexene with H2O2 over peroxytungstate-organic complex catalysts

被引:104
作者
Deng, YQ [1 ]
Ma, ZF [1 ]
Wang, K [1 ]
Chen, J [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Environm & Appl Catalysis, Lanzhou 730000, Peoples R China
关键词
D O I
10.1039/a908889j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Directly catalytic oxidation of cyclohexene to adipic acid with hydrogen peroxide over environmentally benign peroxytungstate-organic complex catalysts is performed with excellent yields and selectivities, without any organic solvent and harmful phase-transer catalyst.
引用
收藏
页码:275 / 276
页数:2
相关论文
共 7 条
  • [1] Bonsignore S., 1997, Eur. Patent EP, Patent No. [0,593,129 A1, 0593129]
  • [2] KNOPSGERRITS PP, 1994, STUD SURF SCI CATAL, V84, P1411
  • [3] OXIDATIVE CLEAVAGE OF OLEFINS INTO CARBOXYLIC-ACIDS WITH HYDROGEN-PEROXIDE BY TUNGSTIC ACID
    OGUCHI, T
    URA, T
    ISHII, Y
    OGAWA, M
    [J]. CHEMISTRY LETTERS, 1989, (05) : 857 - 860
  • [4] A "green" route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide
    Sato, K
    Aoki, M
    Noyori, R
    [J]. SCIENCE, 1998, 281 (5383) : 1646 - 1647
  • [5] A practical method for epoxidation of terminal olefins with 30% hydrogen peroxide under halide-free conditions
    Sato, K
    Aoki, M
    Ogawa, M
    Hashimoto, T
    Noyori, R
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (23) : 8310 - 8311
  • [6] TAKAHIRO I, 1995, TETRAHEDRON LETT, V36, P1523
  • [7] VENTURELLO C, 1986, Patent No. 122804