A helicopter view of microwave application to chemical processes: reactions, separations, and equipment concepts

被引：108

作者：

Stefanidis, Georgios D. ^{[1
]}

Munoz, Alexander Navarrete ^{[1
]}

Sturm, Guido S. J. ^{[1
]}

Stankiewicz, Andrzej ^{[1
]}

机构：

[1] Delft Univ Technol, Proc & Energy Dept, NL-2628 CB Delft, Netherlands

来源：

REVIEWS IN CHEMICAL ENGINEERING | 2014年 / 30卷 / 03期

关键词：

microwaves; process intensification; reactions; separations; CONTROL HYDRODYNAMIC INSTABILITIES; OF-THE-ART; ASSISTED CATALYTIC TRANSFORMATIONS; CONVENTIONAL REACTION CONDITIONS; GAS-PHASE CATALYSIS; ORGANIC-SYNTHESIS; ESSENTIAL OIL; ACTIVATED CARBONS; EVAPORATIVE CRYSTALLIZATION; TEMPERATURE DISTRIBUTION;

D O I：

10.1515/revce-2013-0033

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

We present a helicopter view of microwave technology application to various reaction and separation processes, including liquid-phase organic syntheses, gas-solid catalytic reactions, polymerizations, extraction, distillation, crystallization, membrane separation, and adsorbent regeneration/dehydration. The overarching aim is to demonstrate the breadth of potential applications of microwave technology to chemical industry, with particular attention to separations, as this is a less explored microwave application area. In this context, some key findings, opinions, and developments in the relevant literature are summarized. In addition, the present microwave equipment concepts for chemical processes are critically reviewed and new ones are put forward, as we believe that an important milestone in the road from laboratory-scale microwave experimentation to industrial-scale microwave-assisted chemical processing is the design and development of innovative microwave equipment concepts tailored for specific chemical processes.

引用

页码：233 / 259

页数：27

共 216 条

[1] Mechanistic Investigation into the Accelerated Synthesis of Methacrylate Oligomers via the Application of Catalytic Chain Transfer Polymerization and Selective Microwave Heating [J].

Adlington, Kevin ;

Jones, G. Joe ;

El Harfi, Jaouad ;

Dimitrakis, Georgios ;

Smith, Alastair ;

Kingman, Sam W. ;

Robinson, John P. ;

Irvine, Derek J. .

MACROMOLECULES, 2013, 46 (10) :3922-3930

[2]

Ahmed J., 2007, Handbook of Food Preservation, V2nd, P691

[3] Rapid Crystallization of L-Alanine on Engineered Surfaces by Use of Metal-Assisted and Microwave-Accelerated Evaporative Crystallization [J].

Alabanza, Anginelle M. ;

Pozharski, Edwin ;

Aslan, Kadir .

CRYSTAL GROWTH & DESIGN, 2012, 12 (01) :346-353

[4] Metal-Assisted and Microwave-Accelerated Evaporative Crystallization: Application to L-Alanine [J].

Alabanza, Anginelle M. ;

Aslan, Kadir .

CRYSTAL GROWTH & DESIGN, 2011, 11 (10) :4300-4304

[5] Process Intensification of Reactive Distillation for the Synthesis of n-Propyl Propionate: The Effects of Microwave Radiation on Molecular Separation and Esterification Reaction [J].

Altman, Ernesto ;

Stefanidis, Georgios D. ;

van Gerven, Thomas ;

Stankiewicz, Andrzej I. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (21) :10287-10296

[6] Kinetics study of microwave-assisted solvent extraction of oil from olive cake using hexane Comparison with the conventional extraction [J].

Amarni, Fatiha ;

Kadi, Hocine .

INNOVATIVE FOOD SCIENCE & EMERGING TECHNOLOGIES, 2010, 11 (02) :322-327

[7]

[Anonymous], 1995, Foundations and industrial applications of microwave and radio frequency fields: physical and chemical processes

[8]

[Anonymous], CHEM TODAY

[9]

[Anonymous], 2005, MICROWAVE PROCESSING

[10] ABSOLUTE MEASUREMENTS OF THE THERMAL-CONDUCTIVITY OF MIXTURES OF ALCOHOLS WITH WATER [J].

ASSAEL, MJ ;

CHARITIDOU, E ;

WAKEHAM, WA .

INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1989, 10 (04) :793-803

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