Hydrophobization of starch nanocrystals through esterification in green media

被引：29

作者：

Ren, Lili ^{[1
,2
]}

Dong, Zhao ^{[1
]}

Jiang, Man ^{[2
]}

Tong, Jin ^{[1
]}

Zhou, Jiang ^{[1
]}

机构：

[1] Jilin Univ, Coll Biol & Agr Engn, Minist Educ, Key Lab Bion Engn, Changchun 130022, Peoples R China

[2] Jilin Univ, Coll Chem, Changchun 130022, Peoples R China

来源：

INDUSTRIAL CROPS AND PRODUCTS | 2014年 / 59卷

基金：

中国国家自然科学基金;

关键词：

Starch nanocrystals; Hydrophobization; Esterification modification; Alkenyl succinic anhydride; Acetic anhydride; MAIZE; NANOCOMPOSITES;

D O I：

10.1016/j.indcrop.2014.05.014

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Starch nanocrystals (SNC) were successfully modified through esterification by using dodecenyl succinic anhydride (DDSA), 2-octen-1-ylsuccinic anhydride (OSA) and acetic anhydride (AA) in green media. The chemical modifications were confirmed using FT-IR. The esterification extent of the modified SNC was evaluated by degree of substitution (DS). The modifications imparted hydrophobic character to SNC so that the modified SNC could be dispersed in non-polar solvents such as chloroform, dichloromethane and toluene. It was found that the dispersibility of the modified SNC in non-polar solvents increased with increasing of DS and hydrophobicity of the group replacing the hydroxyl groups in starch. XRD analysis showed that the crystalline structure of SNC was preserved after the modifications. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：115 / 118

页数：4

共 21 条

[1] Thermoplastic starch-waxy maize starch nanocrystals nanocomposites [J].

Angellier, H ;

Molina-Boisseau, S ;

Dole, P ;

Dufresne, A .

BIOMACROMOLECULES, 2006, 7 (02) :531-539

[2] Mechanical properties of waxy maize starch nanocrystal reinforced natural rubber [J].

Angellier, H ;

Molina-Boisseau, S ;

Dufresne, A .

MACROMOLECULES, 2005, 38 (22) :9161-9170

[3] Surface chemical modification of waxy maize starch nanocrystals [J].

Angellier, H ;

Molina-Boisseau, S ;

Belgacem, MN ;

Dufresne, A .

LANGMUIR, 2005, 21 (06) :2425-2433

[4] Optimization of the preparation of aqueous suspensions of waxy maize starch nanocrystals using a response surface methodology [J].

Angellier, H ;

Choisnard, L ;

Molina-Boisseau, S ;

Ozil, P ;

Dufresne, A .

BIOMACROMOLECULES, 2004, 5 (04) :1545-1551

[5] Rapid and environmentally friendly preparation of starch esters [J].

Biswas, Atanu ;

Shogren, R. L. ;

Selling, Gordon ;

Salch, J. ;

Willett, J. L. ;

Buchanan, Charles M. .

CARBOHYDRATE POLYMERS, 2008, 74 (01) :137-141

[6] Physico-Mechanical Properties of Biodegradable Starch Nanocomposites [J].

Garcia, Nancy L. ;

Ribba, Laura ;

Dufresne, Alain ;

Aranguren, Mirta I. ;

Goyanes, Silvia .

MACROMOLECULAR MATERIALS AND ENGINEERING, 2009, 294 (03) :169-177

[7]

Jeon YS, 1999, STARCH-STARKE, V51, P90, DOI 10.1002/(SICI)1521-379X(199903)51:2<90::AID-STAR90>3.3.CO

[8]

2-D

[9] Physical properties of starch nanocrystal-reinforced pullulan films [J].

Kristo, Eleana ;

Biliaderis, Costas G. .

CARBOHYDRATE POLYMERS, 2007, 68 (01) :146-158

[10] Polymer grafting onto starch nanocrystals [J].

Labet, Marianne ;

Thielemans, Wim ;

Dufresne, Alain .

BIOMACROMOLECULES, 2007, 8 (09) :2916-2927

← 1 2 3 →