Rhodium(III)-Catalyzed Ortho Halogenations of N-Acylsulfoximines and Synthetic Applications toward Functionalized Sulfoximine Derivatives

被引：46

作者：

Cheng, Ying ^{[1
]}

Dong, Wanrong ^{[1
]}

Parthasarathy, Kanniyappan ^{[1
]}

Bolm, Carsten ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 03期

关键词：

C-H FUNCTIONALIZATION; BOND FUNCTIONALIZATIONS; ORTHO-BROMINATION; IODINATION; (HETERO)ARENES; CHLORINATION;

D O I：

10.1021/acs.orglett.7b00043

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium(III)-catalyzed ortho brominations and iodinations of N-acylsulfoximines by C-H bond activations have been developed. Subsequent product functionalizations involving cross-coupling reactions provide alkynylated sulfoximine derivatives and benzothiazines with wide potential for further synthetic applications.

引用

页码：726 / 729

页数：4

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