Hydroamination of conjugated dienes catalyzed by transition metal complexes

被引:34
作者
Dzhemilev, U. M. [1 ]
Tolstikov, G. A. [2 ]
Khusnutdinov, R. I. [1 ]
机构
[1] Russian Acad Sci, Inst Petr Chem & Catalysis, Ufa 450075, Bashkortostan, Russia
[2] Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
关键词
ACTIVE METHYLENE-COMPOUNDS; PALLADIUM COMPLEXES; TERPENE AMINE; BUTADIENE; TELOMERIZATION; NICKEL; AMINATION; ISOPRENE; 1,3-DIENES; AMMONIA;
D O I
10.1134/S107042800907001X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The review summarizes published data on the hydroamination of 1,3-dienes with various primary and secondary amines, ammonia, and ammonium salts of mineral acids in the presence of transition metal complexes under homogeneous conditions. The effects of the nature of metal, ligand, initial diene, and amine and reaction conditions on the selectivity of hydroamination are considered, and possible reaction mechanisms are discussed.
引用
收藏
页码:957 / 987
页数:31
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