Peroxidative catalytic oxidation of alcohols catalyzed by heterobinuclear vanadium(V) complexes using H2O2 as terminal oxidizing agents

被引：17
作者：
Kurbah, Sunshine D. [1 ]
Asthana, M. [2 ]
Syiemlieh, Ibanphylla [1 ]
Lal, Ram A. [1 ]
机构：
[1] North Eastern Hill Univ, Dept Chem, Ctr Adv Studies, Shillong 793022, Meghalaya, India
[2] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2018年 / 32卷 / 04期
关键词：
bimetallic vanadium (V); catalysis; oxidation; peroxidative; SELECTIVE AEROBIC OXIDATION; METAL-ORGANIC FRAMEWORK; GOLD NANOPARTICLES; CRYSTAL-STRUCTURE; BENZYL ALCOHOL; EFFICIENT; LIGANDS; AIR; ATMOSPHERE; ALDEHYDES;
D O I：
10.1002/aoc.4299
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Here we report the catalytic oxidation of benzylic alcohol, hetero-aryl alcohols and propargylic alcohols to their corresponding carbonyl compound using heterobimetallic sodium-dioxidovanadium(V) complexes. The present catalytic oxidation studies proceed at 70 degrees C using H2O2 as terminal oxidant. During the whole process, the complexes react with hydrogen peroxide to form peroxo-vanadium(V) species. The present study shows the heterogeneity of pre-catalyst which could be easily recovered and moreover isolation of product is very simple.
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页数：7
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