Catalyst-free selenylation of acylacetylenes with secondary phosphine selenides and water: A short-cut to bis(2-acylvinyl) selenides

被引：5

作者：

Volkov, Pavel A. ^{[1
]}

Gusarova, Nina K. ^{[1
]}

Khrapova, Kseniya O. ^{[1
]}

Telezhkin, Anton A. ^{[1
]}

Ivanova, Nina I. ^{[1
]}

Albanov, Alexander I. ^{[1
]}

Trofimov, Boris A. ^{[1
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, 1 Favorsky St, Irkutsk 664033, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 867卷

关键词：

Secondary phosphine selenides; Selenylating agents; Acylacetylenes; Bis(2-acylvinyl) selenides; SOLVENT-FREE; OXIDES; ORGANOSELENIUM; SULFIDES; ALKYNES; ROUTE;

D O I：

10.1016/j.jorganchem.2017.09.031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Secondary phosphine selenides react with acylacetylenes in water to form bis(2-acylvinyl) selenides. The reaction proceeds without catalyst and organic solvent under mild conditions (70-72 degrees C, 3 h), the corresponding divinyl selenides being isolated as a mixture of (Z, Z)-and (E, Z)-isomers in a yield of up to 78%. (C) 2017 Published by Elsevier B.V.

引用

页码：79 / 85

页数：7

共 9 条

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