Optical properties of carbon nanotubes in a composite material: The role of dielectric screening and thermal expansion

We report on environmental effects on the optical properties of single-wall carbon nanotubes in a gelatin-based composite material designed to foster their photoluminescence. We show that the dielectric screening of excitons due to the surrounding medium is responsible for a sizeable shift of the luminescence lines, which hardly depends on the tube geometry. In contrast, the temperature dependence (from 4 to 300 K) of the luminescence is clearly chirality dependent; the first and second excitonic lines shift in opposite directions with a magnitude that can be related quantitatively to a strain-induced modification of the electronic structure due to an expansivity mismatch between the nanotube and the matrix. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3116723]