Synthesis and comparative behavior of ruthena(II)cycles bearing benzene ligand in the radical polymerization of styrene and vinyl acetate

被引：6

作者：

Martinez Cornejo, Vanessa ^{[1
,2
]}

Olvera Mancilla, Jessica ^{[1
]}

Lopez Morales, Salvador ^{[1
]}

Oviedo Fortino, Jose Alberto ^{[2
]}

Hernandez-Ortega, Simon ^{[2
]}

Alexandrova, Larissa ^{[1
]}

Le Lagadec, Ronan ^{[2
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico

[2] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 799-800卷

关键词：

Cyclometalated ruthenium complexes; Ligand exchange; Atom transfer radical polymerization; CYCLOMETALATED RUTHENIUM(II) COMPLEXES; GLUCOSE-OXIDASE; CATALYTIC-ACTIVITIES; ELECTRON-TRANSFER; ADDITIONS; CHEMISTRY; PEROXIDASE; DISTANCE;

D O I：

10.1016/j.jorganchem.2015.10.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of half-sandwich ruthenium(II) complexes of the type [Ru(eta(6)-C6H6)(NnC)LIPF6 (L = PPh3, P(nBu)(3), SbPh3, MeCN), bearing cyclometalated N,N-dimethylbenzylamine (la d) and 2-phenylpyridine (2a -d) moieties, has been efficiently prepared by ligand substitution. The molecular structures of the new compounds were unequivocally determined by single-crystal X-ray diffraction. The catalytic activity of the complexes in the radical polymerizations of styrene and vinyl acetate was evaluated, and a comparative structure activity analysis was performed. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：299 / 310

页数：12

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