A Honeycomb-Layered Oxide Cathode for Sodium-Ion Batteries with Suppressed P3-O1 Phase Transition

被引：125
作者：
You, Ya [1 ,2 ]
Kim, Sang Ok [1 ,2 ]
Manthiram, Arumugam [1 ,2 ]
机构：
[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA
[2] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
来源：
ADVANCED ENERGY MATERIALS | 2017年 / 7卷 / 05期
关键词：
LITHIUM-ION; ELECTRODE; ANODE; INTERCALATION; SUBSTITUTION;
D O I：
10.1002/aenm.201601698
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Mg-substituted Na3Ni2-xMgxSbO6 cathode materials are synthesized via a scalable high-temperature solid-state method to improve the cyclability of the honey-comb-layered oxide cathode in sodiumion batteries. The partial substitution of Ni2+ by Mg2+ in the transition-metal layer suppresses the electrochemically unfavorable P3-O1 transition and enlarges the lattice parameters to bring improved performance with respect to capacity retention, Coulombic efficiency, and Na (de) intercalation kinetics.
引用
收藏
页数：7
相关论文
共 34 条
  • [1] Berthelot R, 2011, NAT MATER, V10, P74, DOI [10.1038/nmat2920, 10.1038/NMAT2920]
  • [2] Na0.67Mn1-xMgxO2 (0 ≤ x ≤ 0.2): a high capacity cathode for sodium-ion batteries
    Billaud, Juliette
    Singh, Gurpreet
    Armstrong, A. Robert
    Gonzalo, Elena
    Roddatis, Vladimir
    Armand, Michel
    Rojob, Teofilo
    Bruce, Peter G.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (04) : 1387 - 1391
  • [3] ELECTROCHEMICAL INTERCALATION OF SODIUM IN NAXCOO2 BRONZES
    DELMAS, C
    BRACONNIER, JJ
    FOUASSIER, C
    HAGENMULLER, P
    [J]. SOLID STATE IONICS, 1981, 3-4 (AUG) : 165 - 169
  • [4] A Layered P2-and O3-Type Composite as a High-Energy Cathode for Rechargeable Sodium-Ion Batteries
    Guo, Shaohua
    Liu, Pan
    Yu, Haijun
    Zhu, Yanbei
    Chen, Mingwei
    Ishida, Masayoshi
    Zhou, Haoshen
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (20) : 5894 - 5899
  • [5] Na2Ni2TeO6: Evaluation as a cathode for sodium battery
    Gupta, Asha
    Mullins, C. Buddie
    Goodenough, John B.
    [J]. JOURNAL OF POWER SOURCES, 2013, 243 : 817 - 821
  • [6] Na4-M2+/2(P2O7)2 (2/3 7/8, M = Fe, Fe0.5Mn0.5, Mn): A Promising Sodium Ion Cathode for Na-ion Batteries
    Ha, Kwang-Ho
    Woo, Seung Hee
    Mok, Duckgyun
    Choi, Nam-Soon
    Park, Yuwon
    Oh, Seung M.
    Kim, Youngshol
    Kim, Jeongsoo
    Lee, Junesoo
    Nazar, Linda F.
    Lee, Kyu Tae
    [J]. ADVANCED ENERGY MATERIALS, 2013, 3 (06) : 770 - 776
  • [7] High Performance Na0.5[Ni0.23Fe0.13Mn0.63]O2 Cathode for Sodium-Ion Batteries
    Hasa, Ivana
    Buchholz, Daniel
    Passerini, Stefano
    Scrosati, Bruno
    Hassoun, Jusef
    [J]. ADVANCED ENERGY MATERIALS, 2014, 4 (15)
  • [8] Structural evolution and electrochemistry of monoclinic NaNiO2 upon the first cycling process
    Huon Han, Man
    Gonzalo, Elena
    Casas-Cabanas, Montse
    Rojo, Teofilo
    [J]. JOURNAL OF POWER SOURCES, 2014, 258 : 266 - 271
  • [9] One-dimensional nanostructured design of Li1+x(Mn1/3Ni1/3Fe1/3)O2 as a dual cathode for lithium-ion and sodium-ion batteries
    Kalluri, Sujith
    Pang, Wei Kong
    Seng, Kuok Hau
    Chen, Zhixin
    Guo, Zaiping
    Liu, Hua Kun
    Dou, Shi Xue
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (01) : 250 - 257
  • [10] Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application
    Kim, Donghan
    Lee, Eungje
    Slater, Michael
    Lu, Wenquan
    Rood, Shawn
    Johnson, Christopher S.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2012, 18 : 66 - 69
1234