Atomically and Electronically Coupled Pt and CoO Hybrid Nanocatalysts for Enhanced Electrocatalytic Performance

被引:267
作者
Meng, Chao [1 ]
Ling, Tao [1 ,2 ]
Ma, Tian-Yi [2 ]
Wang, Hui [3 ]
Hu, Zhenpeng [4 ]
Zhou, Yue [1 ]
Mao, Jing [1 ]
Du, Xi-Wen [1 ]
Jaroniec, Mietek [5 ]
Qiao, Shi-Zhang [1 ,2 ]
机构
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin Key Lab Composite & Funct Mat, Key Lab Adv Ceram & Machining Technol,Minist Educ, Tianjin 300072, Peoples R China
[2] Univ Adelaide, Sch Chem Engn, Adelaide, SA 5005, Australia
[3] Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China
[4] Nankai Univ, Sch Phys, Tianjin 300071, Peoples R China
[5] Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA
基金
中国国家自然科学基金; 澳大利亚研究理事会;
关键词
OXYGEN REDUCTION; BIFUNCTIONAL ELECTROCATALYST; PLATINUM; OXIDE; WATER; NANOPARTICLES; NANOCRYSTALS; CATALYSIS; METALS; CHALLENGES;
D O I
10.1002/adma.201604607
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Atomically and electronically coupled Pt and CoO hybrid nanocatalysts are fabricated for electrocatalytic oxygen reduction reaction. The atomic coupling between the Pt and the CoO endows precise control of the atomic interface between the Pt and the CoO, which directly results in electron donation from the CoO to the Pt, and thus favorable tuning of the electronic structure of the Pt.
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页数:8
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