Melting of bcc transition metals and icosahedral clustering

被引：18
作者：
Ross, Marvin
Boehler, Reinhard
Japel, Stefanie
机构：
[1] Max Planck Inst Chem, D-55020 Mainz, Germany
[2] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2006年 / 67卷 / 9-10期
关键词：
D O I：
10.1016/j.jpcs.2006.05.009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In contrast to polyvalent metals, transition metals have low melting slopes (dT/dP) that are due to partially filled d-bands that allow for a lowering of liquid phase energy through s-d electron transfer and the formation of local structures. In the case of bcc transition metals, we show that the apparent discrepancy of diamond-anvil cells (DAC) melting measurements with shock melting of Mo can be understood by reexamining the shock data for V and Ta and introducing the presence of an icosahedral short range order (ISRO) melt phase. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2178 / 2182
页数：5
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