Syntheses and crystal structures of [Fe(m-NO2phtpy)2](ClO4)2 and [Fe(m-Clphtpy)2](ClO4)2 (m-NO2phtpy=4'-(3-nitrophenyl)-2,2':6',2aEuro3-terpyridine and m-Clphtpy=4'-(3-chlorophenyl)-2,2':6',2aEuro3-terpyridine)

被引：2
作者：
Fu, W. -W. [1 ,2 ]
Zhang, F. -X. [1 ,2 ]
Kuang, D. -Z. [1 ,2 ]
机构：
[1] Gen Coll & Univ Hunan Prov, Key Lab Funct Organometall Mat, Jishou, Peoples R China
[2] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 05期
关键词：
iron(II) compound; 4 '-(3-nitrophenyl)-2,2 ':6 ',2 ''-terpyridine; 4 '-(3-chlorophenyl)-2,2 ':6 ',2 ''-terpyridine; crystal structure; FE(II) COMPLEXES; METAL; IRON(II); POLYMERS; LIGAND; RU;
D O I：
10.1134/S002247661405014X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two iron compounds [Fe(m-NO(2)phtpy)(2)](ClO4)(2) 1 and [Fe(m-Clphtpy)(2)](ClO4)(2) 2 are synthesized and their structures are determined by single crystal X-ray diffraction. Crystal data for 1 are: orthorhombic, space group Pcca, a = 25.471(4) , b = 10.8182(18) , c = 14.682(2) , Z = 4. Crystal data for 2 are: orthorhombic, space group Pnna, a = 14.521(2) , b = 23.980(4) , c = 23.142(4) , and Z = 8. The iron atoms are coordinated by six N atoms from two terpyridines in both compounds. These two compounds are all linked by hydrogen bonds with C as donor and O as acceptor into a 3D network for 1 and a 2D network for 2. If viewed along the c direction in 1 and the a direction in 2, both compounds show the ordered figure with terpyridine overlapped as a square and the phenyl rings overlapped as a rectangle or a square.
引用
收藏
页码：895 / 900
页数：6
相关论文
共 25 条
[1]   Red and blue luminescent metallo-supramolecular coordination polymers assembled through π-π interactions [J].
Alcock, NW ;
Barker, PR ;
Haider, JM ;
Hannon, MJ ;
Painting, CL ;
Pikramenou, Z ;
Plummer, EA ;
Rissanen, K ;
Saarenketo, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (09) :1447-1461
[2]   New functional polymers and materials based on 2,2′:6′,2"-terpyridine metal complexes [J].
Andres, PR ;
Schubert, US .
ADVANCED MATERIALS, 2004, 16 (13) :1043-1068
[3]   Expanding the 4,4′-bipyridine ligand:: Structural variation in {M(pytpy)2}2+ complexes (pytpy=4′-(4-pyridyl)-2,2′:6′,2"-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer {[Ru(pytpy)(Hpytpy)]}n3n+ [J].
Beves, Jonathon E. ;
Bray, David J. ;
Clegg, Jack K. ;
Constable, Edwin C. ;
Housecroft, Catherine E. ;
Jolliffe, Katrina A. ;
Kepert, Cameron J. ;
Lindoy, Leonard F. ;
Neuburger, Markus ;
Price, David J. ;
Schaffner, Silvia ;
Schaper, Frank .
INORGANICA CHIMICA ACTA, 2008, 361 (9-10) :2582-2590
[4]   A terpyridyl-imidazole (tpy-HImzPh3) based bifunctional receptor for multichannel detection of Fe2+ and F- ions [J].
Bhaumik, Chanchal ;
Das, Shyamal ;
Maity, Dinesh ;
Baitalik, Sujoy .
DALTON TRANSACTIONS, 2011, 40 (44) :11795-11808
[5]   Directional self assembly of a double-helical complex of a solubilised septipyridine [J].
Constable, EC ;
Neuburger, M ;
Smith, DR ;
Zehnder, M .
CHEMICAL COMMUNICATIONS, 1996, (16) :1917-1918
[6]   Toward an Iron(II) Spin-Crossover Grafted Phosphazene Polymer [J].
Davidson, Ross J. ;
Ainscough, Eric W. ;
Brodie, Andrew M. ;
Jameson, Geoffrey B. ;
Waterland, Mark R. ;
Allcock, Harry R. ;
Hindenlang, Mark D. ;
Moubaraki, Boujemaa ;
Murray, Keith S. ;
Gordon, Keith C. ;
Horvath, Raphael ;
Jameson, Guy N. L. .
INORGANIC CHEMISTRY, 2012, 51 (15) :8307-8316
[7]   Preparation, characterization, and photophysical properties of Pt-M (M = Ru, Re) heteronuclear complexes with 1,10-phenanthrolineethynyl ligands [J].
Fan, Yang ;
Zhang, Li-Yi ;
Dai, Feng-Rong ;
Shi, Lin-Xi ;
Chen, Zhong-Ning .
INORGANIC CHEMISTRY, 2008, 47 (07) :2811-2819
[8]   Synthesis, Crystal Structure and Properties of the Nickel(II) 4′-(p-methoxylphenyl)-2,2′:6′,2"-terpyridine Complex [J].
Fu Wei-Wei ;
Kuang Dai-Zhi ;
Zhang Fu-Xing ;
Liu Yang ;
Li Wei ;
Kuang Yun-Fei .
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (03) :654-658
[9]   Supramolecular frameworks composed of Ru(II), Cu(II), Zn(II), Ni(II) and Fe(II) complexes having tridentate 4′-chloro-2,2′: 6′ 2"-terpyridine ligand and 1:1 or 1:2 ratios of metal and ligand [J].
Huang, Wei ;
Qian, Huifen .
JOURNAL OF MOLECULAR STRUCTURE, 2008, 874 (1-3) :64-76
[10]   Studies of the isomerization and photophysical properties of a novel 2,2′:6′,2"-terpyridine-based ligand and its complexes [J].
Li, Dongmei ;
Zhang, Qiong ;
Wang, Peng ;
Wu, Jieying ;
Kan, Yuhe ;
Tian, Yupeng ;
Zhou, Hongping ;
Yang, Jiaxiang ;
Tao, Xutang ;
Jiang, Minhua .
DALTON TRANSACTIONS, 2011, 40 (32) :8170-8178
123