The Colloidal Suprastructure of Smart Microgels at Oil-Water Interfaces

被引：94

作者：

Brugger, Bastian ^{[1
]}

Ruetten, Stephan ^{[2
,3
]}

Phan, Kim-Ho ^{[2
,3
]}

Moeller, Martin ^{[2
,3
]}

Richtering, Walter ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Phys Chem, D-52056 Aachen, Germany

[2] Rhein Westfal TH Aachen, DWI eV, D-52074 Aachen, Germany

[3] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 22期

关键词：

copolymerization; de-emulsification; emulsions; gels; interfaces; SOLID PARTICLES; ELECTRON MICROSCOPY; EMULSIONS; MICROSTRUCTURE; SUSPENSIONS; LINE; PH;

D O I：

10.1002/anie.200900239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oil on troubled waters: Stimuli-sensitive emulsions have been used to prepare temperature- and pH-responsive microgels. The emulsion stability at oil-water interfaces is not governed by the particle packing density, and structural changes induced by the interface lead to connections between the individual microgels (see picture; scale bar 1 μm), which behave very differently compared to solidparticle-stabilized emulsions. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3978 / 3981

页数：4

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