Group II metal-directed structural variation of coordination compounds derived from 5-[N-acetato(4-pyridyl)]tetrazolate ligand

被引：19
作者：
Zhou, Yi [1 ]
Yang, Gao-Wen [1 ]
Li, Qiao-Yun [1 ]
Liu, Ke
Gu, Guo-Qing [1 ]
Ma, Yun-Sheng [1 ]
Yuan, Rong-Xin [1 ]
机构：
[1] Changshu Inst Technol, Jiangsu Lab Adv Funct Mat, Dept Chem & Mat Engn, Changshu 215500, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 06期
关键词：
Tetrazole; Carboxylate; Group II metal ions; Crystal structure; Luminescence; HUISGEN 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY APPROACH; 5-SUBSTITUTED; 1H-TETRAZOLES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; ORGANIC FRAMEWORK; HYDROGEN STORAGE; TETRAZOLE LIGAND; POLYMERS; COMPLEXES;
D O I：
10.1016/j.ica.2008.08.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of MCl2 (M = Mg, Ca, Sr, Ba) and a4-ptz (a4-ptz = 5-[N-acetato (4-pyridyl)]tetrazolate) potassium salt in water, respectively, and produced four new complexes [Mg(H2O)(6)] center dot (a4-ptz)(2) center dot 2H(2)O (1), [Ca(a4-ptz)(2)(H2O)(2)](n) center dot 2nH(2)O (2), [Sr(a4-ptz)(2)(H2O)(2)]n center dot 2nH(2)O (3), [Ba-4(a4-ptz)(8)(H2O)(8)](n) center dot 4nH(2)O (4). These compounds were structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Compound 1 has mononuclear structure bearing distinct intermolecular hydrogen-bond interactions to form a three-dimensional supramolecular network. While compounds 2-4 have one-dimensional polymeric chains that are bridged by two water molecules linker, respectively. The luminescence properties of 1-4 were investigated at room temperature in the solid state. (C) 2008 Elsevier B. V. All rights reserved.
引用
收藏
页码：1723 / 1729
页数：7
相关论文
共 42 条
  • [1] Heavy alkaline-earth polyether carboxylates. The crystal structure of {Ca[OOC(CH2)O(CH2)(2)](2)O(H2O)(2)}(2)
    Bahl, AM
    Krishnaswamy, S
    Massand, NG
    Burkey, DJ
    Hanusa, TP
    [J]. INORGANIC CHEMISTRY, 1997, 36 (23) : 5413 - 5415
  • [2] Thermal and light-induced spin transition in the high- and low-temperature structure of [Fe(0.3)5Ni(0.65)(mtz)(6)](ClO4)(2)
    Buchen, T
    Schollmeyer, D
    Gutlich, P
    [J]. INORGANIC CHEMISTRY, 1996, 35 (01) : 155 - 161
  • [3] An expedient route to the tetrazole analogues of α-amino acids
    Demko, ZP
    Sharpless, KB
    [J]. ORGANIC LETTERS, 2002, 4 (15) : 2525 - 2527
  • [4] Demko ZP, 2002, ANGEW CHEM INT EDIT, V41, P2110, DOI 10.1002/1521-3773(20020617)41:12<2110::AID-ANIE2110>3.0.CO
  • [5] 2-7
  • [6] Demko ZP, 2002, ANGEW CHEM INT EDIT, V41, P2113, DOI 10.1002/1521-3773(20020617)41:12<2113::AID-ANIE2113>3.0.CO
  • [7] 2-Q
  • [8] Preparation of 5-substituted 1H-tetrazoles from nitriles in water
    Demko, ZP
    Sharpless, KB
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (24) : 7945 - 7950
  • [9] Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites
    Dinca, Mircea
    Dailly, Anne
    Liu, Yun
    Brown, Craig M.
    Neumann, Dan. A.
    Long, Jeffrey R.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) : 16876 - 16883
  • [10] Observation of Cu2+-H2 interactions in a fully desolvated sodalite-type metal-organic framework
    Dinca, Mircea
    Han, Won Seok
    Liu, Yun
    Dailly, Anne
    Brown, Craig M.
    Long, Jeffrey R.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (09) : 1419 - 1422
12345