A cube in a tetrahedron:: Microwave-assisted synthesis of an octametallic FeIII cluster

被引：61
作者：
Gass, Ian A.
Milios, Constantinos J.
Whittaker, A. Gavin
Fabbiani, Francesca P. A.
Parsons, Simon
Murrie, Mark
Perlepes, Spyros P. [1 ]
Brechin, Euan K.
机构：
[1] Univ Patras, Dept Chem, Patras 26504, Greece
[2] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[3] Univ Glasgow, Dept Chem, Glasgow G12 9UY, Lanark, Scotland
来源：
INORGANIC CHEMISTRY | 2006年 / 45卷 / 14期
关键词：
D O I：
10.1021/ic0607843
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The microwave-assisted reaction of Fe(O2CMe)(2) with salicylaldoxime (saoH(2)) in pyridine produces an octametallic cluster in crystalline form in 2 min. The core describes a cube encapsulated in a tetrahedron, while sao(2-) exhibits a novel coordination mode.
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收藏
页码：5281 / 5283
页数：3
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