Formation of metastable bc8 phase from crystalline Si0.5Ge0.5 by high-pressure torsion

被引:15
作者
Ikoma, Yoshifumi [1 ]
Yamasaki, Terumasa [1 ]
Shimizu, Takahiro [1 ]
Takaira, Marina [1 ]
Kohno, Masamichi [2 ,3 ]
Guo, Qixin [4 ]
McCartney, Martha R. [5 ]
Smith, David J. [5 ]
Arai, Yasutomo [6 ]
Horita, Zenji [4 ,7 ,8 ]
机构
[1] Kyushu Univ, Dept Mat Sci & Engn, Fukuoka 8190395, Japan
[2] Kyushu Univ, Dept Mech Engn, Fukuoka 8190395, Japan
[3] Kyushu Univ, Int Inst Carbon Neutral Energy Res I2CNER, Fukuoka 8190395, Japan
[4] Saga Univ, Synchrotron Light Applicat Ctr, Saga 8408502, Japan
[5] Arizona State Univ, Dept Phys, Tempe, AZ 85287 USA
[6] Japan Aerosp Explorat Agcy, Kibo Utilizat Ctr, Tsukuba, Ibaraki 3058505, Japan
[7] Kyushu Inst Technol, Grad Sch Engn, Kitakyushu, Fukuoka 8048550, Japan
[8] Kumamoto Univ, Magnesium Res Ctr, Kumamoto 8608555, Japan
基金
日本学术振兴会;
关键词
Severe plastic deformation; High-pressure torsion; Semiconductors; Phase transformations; Metastable phase; HRTEM; ELECTRON-MICROSCOPY ANALYSIS; ULTRAFINE-GRAINED MATERIALS; SEVERE PLASTIC-DEFORMATION; NANOGRAINED SILICON; AMORPHOUS PHASES; GERMANIUM; TRANSFORMATION; TRANSITION; GE; SI;
D O I
10.1016/j.matchar.2020.110590
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Si0.5Ge0.5 crystals were subjected to severe plastic deformation using high-pressure torsion (HPT). A metastable body-centered-cubic phase having a bc8 structure was formed by HPT processing with anvil rotations. High resolution transmission electron microscopy analysis revealed that nanograins having diamond-cubic (dc) and bc8 phases were present in the HPT-processed sample. The bc8 phase was reverse transformed back to the dc phase after annealing. The resistivity of the crystalline Si0.5Ge0.5 (similar to 9 x 10(-3) Omega.cm) increased by roughly a factor of 6 after compression, and remained on the same order of magnitude but decreased slightly after 10 anvil rotations despite the grain refinement. These results indicate that the electrical behavior of bc8-Si0.5Ge0.5 is similar to that of bc8-Si.
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页数:5
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