Effective donor abilities of E-t-Bu and EPh (E=0, S. Se, Te) to a high valent transition metal

被引：26

作者：

Bemowski, Ross D. ^{[1
]}

Singh, Amrendra K. ^{[1
]}

Bajorek, Bailey J. ^{[1
]}

DePorre, Yvonne ^{[1
]}

Odom, Aaron L. ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 32期

基金：

美国国家科学基金会;

关键词：

NITRIDO COMPLEXES; PI-DONATION; CHROMIUM(VI); CHEMISTRY; CARBONYLS; LIGANDS; DESIGN;

D O I：

10.1039/c4dt01314j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Amido rotation in the chromium(m), d(0)-system NCr(NP2I)(2)X is under investigation as a method for the parameterization of ligands for their donor properties toward high valent metals. In this study, two new series were prepared and studied based on chalcogenide tigands, X = EBut and EPh and where E = 0, S. Se, Te; the OPh and SPh compounds were previously reported. The ligand donor parameters for these ligands correlate with the Cr-E-C angles in these chatcogenide series. In addition, it was found that NBO calculated overlaps and DFT calculated bond dissociation enthalpies correlate within X = halide-, EBut-and EPh-series. All of the new complexes were characterized by X-ray diffraction.

引用

页码：12299 / 12305

页数：7

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